GCMS method 508 calibration data sheet, Feb 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\022102\CALCK.D Vial: 10 Acq On : 21 Feb 2002 10:41 pm Operator: McLean Sample : CAL CHECK Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Feb 22 10:28:18 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Fri Feb 22 10:27:54 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.58 150 1241665 20.00 ug/L 0.00 10) Naphthalene-d8 13.06 136 2968130 20.00 ug/L 0.00 17) Acenaphthene-diO 18.17 164 1587791 20.00 ug/L 0.00 29) Phenanthrene-diO 22.53 188 2537811 20.00 ug/L 0.00 38) Chrysene-dl2 30.36 240 2370581 20.00 ug/L 0.00 44) Perylene-dl2 34.22 264 1744179 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.57 74 715057 19.04 ug/L 100 3) bis(2-chloroethyl) ether 9.01 93 1166317 19.84 ug/L 96 4) 1,3 - Dichlorobenze 9.41 146 1055891 19.02 ug/L 100 5) 1,4 - Dichlorobenzene 9.62 146 1037784 18.81 ug/L 98 6) 1,2 - Dichlorobenzene 10.00 146 993305 19.45 ug/L 98 7) 2,2 1 - oxybis (l-Chloropr 10.47 45 2549076 17.93 ug/L 99 8) N-Nitroso-di-n-propylamine 10.80 70 873732 19.38 ug/L 99 9) Hexachloroethane 10.89 117 414458 18.59 ug/L 97 11) Nitrobenzene 11.14 77 1211705 17.51 ug/L 96 12) Isophorone 11.87 82 2335358 18.50 ug/L 99 13) bis(2-Chloroethoxy) methan 12.60 93 1394524 18.23 ug/L 98 14) 1,2,4-Trichlorobenzene 12.94 180 783078 18.55 ug/L 99 15) Naphthalene 13.12 128 2905318 18.61 ug/L 100 16) Hexachlorobutadiene 13.56 225 449937 19.19 ug/L 97 18) Hexachlorocyclopentadiene 15.64 237 276258 17.79 ug/L 97 19) 2-chloronaphthalene 16.55 162 1713381 18.88 ug/L 99 20) Dimethylphthalate 17.63 163 2016381 18.63 ug/L 99 21) 2,6-Dinitrotoluene 17.74 165 418046 18.92 ug/L 99 22) Acenaphthylene 17.73 152 2400968 19.25 ug/L 99 23) Acenaphthene 18.26 153 1614669 18.63 ug/L 98 24) 2,4-Dinitrotoluene 18.89 165 626629 19.76 ug/L 100 25) Diethylphthalate 19.77 149 1845346 19.90 ug/L 100 26) 4-Chlorophenyl-phenyl ethe 19.93 204 928946 19.27 ug/L 98 27) Fluorene 19.80 166 1912479 19.36 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.38 77 2443613 17.25 ug/L 99 30) N-Nitrosodiphenylamine 20.30 169 1380184 20.38 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.35 248 529277 19.75 ug/L 95 32) Hexachlorobenzene 21.39 284 530420 19.23 ug/L 94 33) Phenanthrene 22.60 178 2725542 18.53 ug/L 98 34) Anthracene 22.75 178 2760791 19.55 ug/L 100 35) Di-n-butylphthalate 24.69 149 3353993 19.73 ug/L 99 36) Fluoranthene 26.10 202 3120195 18.43 ug/L 98 39) Pyrene 26.73 202 3309793 17.18 ug/L 98 40) Butylbenzylphthalate 29.09 149 1460939 17.70 ug/L 95 41) Benzo (a) antracene 30.32 228 2837874 18.25 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.95 149 2039366 18.97 ug/L 99 43) Chrysene 30.42 228 2692096 17.76 ug/L 99 45) Di-n-Octylphthalate 32.79 149 3208873 17.94 ug/L 98 46) Benzo (b) fluoranthene 33.28 252 2739063 18.77 ug/L 99

(#) = qualifier out of range (m) = manual integration CALCK.D 5080202.M Wed Feb 27 06:06:53 2002 Page 1

NYC-WTC_000052351