GCMS method 508 calibration data sheet, Feb 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

.ta File : C:\MSDCHEM\1\DATA\022102\CAL4.D Vial: 6 q On : 21 Feb 2002 7:25 pm Operator: McLean mple : 40 MIX Inst : Instrumen SC : Multiplr: 1.00 Integration Params: BENZO.P ant Time: Feb 27 06:06:18 2002 <Quant Results File: 5080202.RES

ant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) tie : Quantitation For Method 508gcscan st Update : Mon Feb 25 19:17:14 2002 sponse via : Initial Calibration taAcq Meth : 508SCAN

nternal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.59 150 1259365 20.00 ug/L 0.00 10) Naphthalene-d8 13.07 136 2856449 20.00 ug/L 0.00 17) Acenaphthene-diO 18.18 164 1482098 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.54 188 2436185 20.00 ug/L 0.00 38) Chrysene-dl2 30.37 240 2073436 20.00 ug/L 0.00 44) Perylene-dl2 34.23 264 1445802 20.00 ug/L 0.00

ystem Monitoring Compounds 37) 2,4-ddd surr 27.47 235 23134 0.60 ug/L 0.00 Spiked Amount 5.000 Recovery = 12.00%

arget Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 1422905 37.36 ug/L 100 3) bis(2-chloroethyl) ether 9.04 93 2058003 34.52 ug/L 100 4) 1,3 - Dichlorobenze 9.43 146 1998012 35.49 ug/L 100 5) 1,4 - Dichlorobenzene 9.63 146 1999167 35.73 ug/L 100 6) 1,2 - Dichlorobenzene 10.01 146 1822193 35.18 ug/L 100 7) 2,2 ' - oxybis (l-Chloropr 10.48 45 5076566 35.21 ug/L 100 8) N-Nitroso-di-n-propylamine 10.84 70 1632852 35.70 ug/L 100 9) Hexachloroethane 10.90 117 800387 35.39 ug/L 100 11) Nitrobenzene 11.17 77 2521594 37.87 ug/L 100 12) Isophorone 11.89 82 4594183 37.83 ug/L 100 13) bis(2-Chloroethoxy) methan 12.62 93 2761967 37.52 ug/L 100 14) 1,2,4-Trichlorobenzene 12.94 180 1539585 37.90 ug/L 100 15) Naphthalene 13.14 128 5612523 37.36 ug/L 100 16) Hexachlorobutadiene 13.57 225 855090 37.91 ug/L 100 18) Hexachlorocyclopentadiene 15.65 237 652420 45.01 ug/L 100 19) 2-chloronaphthalene 16.56 162 3282119 38.75 ug/L 100 20) Dimethylphthalate 17.67 163 4003072 39.62 ug/L 100 21) 2,6-Dinitrotoluene 17.77 165 832067 40.35 ug/L 100 22) Acenaphthylene 17.74 152 4546499 39.05 ug/L 100 23) Acenaphthene 18.28 153 3108525 38.43 ug/L 100 24) 2,4-Dinitrotoluene 18.93 165 1228397 41.50 ug/L 100 25) Diethylphthalate 19.79 149 3449455 39.85 ug/L 100 26) 4-Chlorophenyl-phenyl ethe 19.95 204 1752424 38.94 ug/L 100 27) Fluorene 19.82 166 3566189 38.68 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.41 77 5089797 38.50 ug/L 100 20) N-Nitrosodiphenylamine 20.34 169 2475287 38.07 ug/L 100 51) 4-Bromophenyl-phenyl ether 21.37 248 993242 38.61 ug/L 100 32) Hexachlorobenzene 21.40 284 1004239 37.93 ug/L 100 33) Phenanthrene 22.61 178 5296382 37.50 ug/L 100 54) Anthracene 22.77 178 5137274 37.90 ug/L 100 55) Di-n-butylphthalate 24.70 149 6397496 39.20 ug/L 100 56) Fluoranthene 26.12 202 6247316 38.45 ug/L 100 59) Pyrene 26.75 202 6441310 38.23 ug/L 100 10) Butylbenzylphthalate 29.11 149 2929720 40.59 ug/L 100 11) Benzo (a) antracene 30.34 228 5352259 39.34 ug/L 100 12) Bis (2-ethylhexyl) phthala 30.96 149 3839639 40.84 ug/L 100 ;3) Chrysene 30.45 228 5039670 38.01 ug/L 100 =5) Di-n-Octylphthalate 32.81 149 6498860 43.84 ug/L 100 =6) Benzo (b) fluoranthene 33.30 252 4809114 39.76 ug/L 100

t) = qualifier out of range (m) = manual integration L4.D 5080202.M Wed Feb 27 06:06:22. 2002 Page 1

NYC-WTC_000052343