GCMS results for sample AE00739, Jan 29 2002

NYC 9/11 Public Portal Document

1 tupuliu IS DO.

Data File : C : \MSDCHEM\1\5973N\02JAN16\00739. D Vial: 7 • Acq On : 16 Jan 2002 8:07 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 5 Acetic acid, 3-[1,3]dioxola... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 5.88 4.64 ug/L 1707030 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 36 2 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ ... 174 C8H14O4 015745-87-6 36 3 Butane, 2-methoxy-2-methyl- $$ E... 102 C6H140 000994-05-8 33 4 Pentanol, 5-amino-_______________ 103 C5H13NO 002508-29-4 9 Abundance Scan 220 (5.885 min): 00739. D (-) m/z 73.10 100.00% 73

5000 43 5.60 5.80 6.00 6.20

lz-> mL 55 TTCTTTTnuit , 0 I | ■ > . > | ■ 87 103 11 '111' ■i ■ ■ ■ ■ i'''1 ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i I’ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 r ■'11 m/z 43.10 23.34% Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73

5000 mTr < i —piry IT 5.60 5.80 6.00 6.20 43 m/ z 41.10 8.99% 27 55 113 0 rpriu i11111'11' • i ■ ■ ■ ■ i • • ■ ‘I .1 " I 1 187 174 T" " rr 1'q 1 " > |1 .. ........... .. I " > I i ■ ■ ■ ■ । ■11 ■ । /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5.60 5.80 6.00 6.20 5000 m/z 45.10 8.73%

43

m/z-> o TTTTTTT 27 P Ppr 87 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 113 p-n-rp-n-rp 174 I' ‘ 1 ' I '

Abundance #9702: Butane, 2-methoxy-2-methyl- $$ Ether, methyl tert-p... ------------------------ 7(3 5.60 5.80 6.00 6.20 m/z 71.10 6.50%

5000 55 87 27 45 0---m I ■ > i • > ■11" <' i ■ ■ • ■ । ■ i1 ■ ■' । • •«• । " 11 ■ > > I ■ । • 111'1111 ■ . . , ■ /pil ov PIpo— m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

10739. D SCAN508.M Thu Jan 17 08:17:52 2002 Page 7

NYC-WTC_000051977