GCMS calibration results, April 23, 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\APR22O2\CAL8O.D Vial: 2 Acq On 22 Apr 2002 9:25 am Operator: Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 22 14:49 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.22 152 424946 20.00 ug/1 -0.02 10) Naphthalene-d8 15.85 136 1553897 20.00 ug/1 -0.02 17) Acenaphthene-diO 21.15 164 890055 20.00 ug/1 -0.02 30) Phenanthrene-diO 25.59 188 1341795 20.00 ug/1 -0.02 39) Chrysene-dl2 33.65 240 919332 20.00 ug/1 -0.02 45) Perylene-dl2 37.88 264 572827 20.00 ug/1 -0.04

System Monitoring Compounds 28) TCMX 0.00 209 0 0.00 ug/L Spiked Amount 10.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds ^'1-1 Qvalue 2) N-nitroso-dimethyl amine 5.87 74 681805 73.72 ug/1 98 3) bis(2-Chloroethyl)ether 11.63 93 1061078 73.71 ug/1 100 4) 1,3-Dichlorobenzene 12.12 146 1175078 79.16 ug/1 100 5) 1,4-Dichlorobenzene 12.26 146 1190353 79.69 ug/1 99 6) 1,2-Dichlorobenzene 12.78 146 1110738 80.07 ug/1 100 7) 2,2'-oxybi s(1-Chioropropan 13.10 45 1431361 71.97 ug/1 98 8) N-Nitroso-di-n-propylamine 13.50 70 699211 74.06 ug/1 99 9) Hexachloroethane 13.62 117 428697 78.33 ug/1 97 11) Nitrobenzene 13.91 77 1032727 75.80 ug/1 99 12) Isophorone 14.56 82 1970846 76.46 ug/1 99 13) bis(2-Chloroethoxy)methane 15.23 93 1276877 76.04 ug/1 99 14) 1,2,4-Trichlorobenzene 15.74 180 983790 83.28 ug/1 98 15) Naphthalene 15.92 128 2969863 79.49 ug/1 99 16) Hexachlorobutadiene 16.45 225 507849 85.97 ug/1 99 18) Hexachiorocyclopentadiene 18.64 237 377668 95.94 ug/1 99 19) 2-Chloronaphthalene 19.42 162 1855093 79.03 ug/1 99 20) Dimethylphthalate 20.51 163 2154974 79.63 ug/1 99 21) 2,6-Dinitrotoluene 20.73 165 509883 78.80 ug/1 95 22) Acenaphthylene 20.68 152 2590377 78.88 ug/1 100 2 3) Acenaphthene 21.25 153 1843279 78.96 ug/1 99 24) 2,4-Dinitrotoluene 21.89 165 668055 78.43 ug/1 99 25) Diethylphthalate 22.65 149 2021165 77.87 ug/1 99 26) 4-Chlorophenyl-phenylether 22.79 204 951124 82.58 ug/1 97 27) Fluorene 22.78 166 1995914 80.74 ug/1 98 2 9) Azobenzen/ 1,2-Diphenylhyd 23.26 77 1969530 71.70 ug/L 96 31) N-Nitrosodiphenylamine 23.19 168 865797 77.57 ug/1 99 32) 4-Bromophenyl-phenylether 24.25 248 550452. 84.51 ug/1 97 (#) = qualifier out of range (m) = manual integration CAL80.D GCMS0412.M Tue Apr 23 10:11:02 2002 Page 1

NYC-WTC_000048997