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GCMS calibration scan data, Sample 5844, April 4 2002

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Instrument scan data for GCMS calibration using deuterated standards on April 4, 2002.

NYC-WTC_000048479–000048487

Folder label: “GCMS X 4/10/02 A 4/15/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\APR03022\5750.D Vial: 17 Acq On 4 Apr 2002 11:27 am Operator: Sample gc/ms scan 3/12 Inst : GC/MS 209 Mise Multiplr: 2.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0408.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 Silane, tetramethyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.12 7.99 ug/1 344241 1,4-Dichlorobenzene-d4 12.25 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Silane, tetramethyl- 88 C4H12Si 000075-76-3 23 2 N-Ethylformamide 73 C3H7NO 000627-45-2 9 3 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 4 1,3-Dioxolane, 2-methyl- 88 C4H802 000497-26-7 7 Abundance Scan 335 (8.124 min): 5750.D (-) m/z 73.00 100.00% 70

5000 43 .................. ) ............ 1 1 i ■ 1 1 1 i 1 1 r 1 i 1 1 1 1 i ■ ' ■ ' i 7.80 8.00 8.20 8.40 1 1 i 1 1 1 ■ I ' 37, |, | 49 5,5. . . 67, । , 87 103 ' i ■ 1 ■ 1 i 1 ' ■ ■ i 1 1 ''' i ■ ' ' ' i ■1 ■ i ■ 1 1 1 I ' m/z 42.95 28.31% m/z->______ 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #62932: Silane, tetramethyl- 70 |

5000 —aid 7.80 8.00 8.20 8.40 m/ z 41.05 10.51% 45 15 I 53 59 88, 'I 1 1 1 1 1 144*4’1 ■ ■ . i । । I miz-> 10 20 30 40 50 60 70 80 90 100 110 1 20 Abundance #292: N-Ethylformamide 30 73 --------------------------- 7.80 8.00 8.20 8.40 5000 m/ z 44.95 10.04% 44 58

15 TIm —11 1 ' 1 ‘I । । , । i ' 1 1 1 r1 1 1 1 । 1 1 ’I , , , । । । । । । , |-i । Tl/Z-> 10 20 30I 40 50 60 70 80 90 100 110 120 Abundance #49423:1,3-Dioxolane, 2-(3-bromo-5,5,5-trichloro-2,2-dimet ________________ 7t3 7.80 8.00 8.20 8.40 m/z 71.00 6.91% 5000

45 .................................... il, 55 67 109115 ‘ ■ i 1 ■ ‘ 1 i ‘ 1 ■ 1 i 1 1 1 1 r1 1 1 ' i ■ ' ■ ■ i ' r 1 1 i 1 I ■ ■ ■ i > ■ ■ ■ i ■ ■ ■ ■ i ■ 1 1 । 1 ■ 1 1 । 1 ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 7.80 8.00 8.20 8.40

5750.D GCMS0408.M Tue Apr 16 08:15:52 2002 Page 1

NYC-WTC_000048484

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NYC-WTC_000048484Source: NYC Law Department, mirrored locally

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