GCMS reference standard results for volatile organics, April-May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\020419\0409REF2.D Vial: 7 Acq On : 19 Apr 2002 2:01 pm Operator: Nefliu Sample : 04/09 ref Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 19 15:46:29 2002 Quant Results File: SCAN020418.RE

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Fri Apr 19 13:40:58 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.38 152 10699668 40.00 ug/1 -0.05 10) Naphthalene-d8 16.54 136 41265134 40.00 ug/1 -0.07 17) Acenaphthene-diO 24.46 164 22114413 40.00 ug/1 -0.06 31) Phenanthrene-diO 31.72 188 33084313 40.00 ug/1 -0.06 39) Chrysene-dl2 39.94 240 24687165 40.00 ug/1 -0.07 45) Perylene-dl2 43.16 264 17264902 40.00 ug/1 -0.03

System Monitoring Compounds 28) TCMX 27.54 207 841782 6.13 ug/1 -0.07 Spiked Amount .000 Recovery = -61.30% 0 6.G Target Compounds Qvalue 2) N-nitrosodimethylamine 4.00 74 1195571m 6.95 ug/1 3) bis(2-Chloroethyl)ether 10.65 93 4987167 14.10 ug/1 99 4) 1.3-Dichlorbenzene 11.11 146 5414706 14.31 ug/1 100 5) 1,4-Dichlorobenzene 11.44 146 5573785 13.58 ug/1 100 6) 1,2-Dichlorobenzene 11.96 146 5355522 14.86 ug/1 100 7) 2,2'oxybis(1-Chloropropane 12.78 45 7595724m 15.25 ug/1 8) N-Nitroso-di-n-propylamine 13.25 43 2832648 15.28 ug/1 99 9) Hexachloroethane 13.26 119 1725175 12.27 ug/1 # 90 11) Nitrobenzene 13.67 77 3692325 12.18 ug/1 99 12) Isophorone 14.78 82 7879212 13.20 ug/1 98 13) bis(2-Chloroethoxy) methan 16.03 93 6437781 15.30 ug/1 97 14) 1,2,4-Trichlorobenzene 16.38 180 4313304 14.71 ug/1 98 15) Naphthalene 16.62 128 15623378 15.87 ug/1 98 16) Hexachlorobutadiene 17.40 225 2052043 15.52 ug/1 98 18) Hexachlorocyclopentadiene 20.58 237 311060 3.05 ug/1 93 19) 2-Chloronaphthalene 21.93 162 9829895 18.20 ug/1 97 20) Acenaphthylene 23.75 152 14342863 14.51 ug/1 98 21) Dimethyl phthalate 23.85 163 11754235 17.77 ug/1 100 22) 2,6-Dinitrotoluene 23.96 77 368823 11.99 ug/1 # 79 23) Acenaphthene 24.60 153 9565758 17.10 ug/1 97 24) 2,4-Dinitrotoluene 25.74 165 1418427 11.66 ug/1 97 25) Fluorene 27.01 166 11693947 18.09 ug/1 97 26) Diethyl phthalate 27.23 149 11108163 18.80 ug/1 99 27) 4-Chlorophenyl-phenylether 27.35 204 5081419 17.47 ug/1 98 29) N-Nitrosodiphenylamine 27.94 168 3007917 14.53 ug/1 # 85 30) Azobenzene 28.03 77 9873892 14.32 ug/1 94 32) Hexachlorobenzene 29.60 284 3226439 19.08 ug/1 98 33) 4-Bromophenyl-phenylether 29.71 248 2901144 18.06 ug/1 91 34) Phenanthrene 31.82 178 16599683 17.98 ug/1 98 35) Anthracene 32.05 178 14615983 15.39 ug/1 98

(#) = qualifier out of range (m) = manual integration 0409REF2.D SCAN020418.M Mon Apr 22 15:31:27 2002 Page 1

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