GCMS reference analysis AE08209, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\APR1702\REFA2.D Vial: 18 Acq On : 18 Apr 2002 12:49 am Operator : Sample : gc/ms scan 4/8 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 18 13:57 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 450800 20.00 ug/1 -0.03 10) Naphthalene-d8 15.84 136 1651802 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.15 164 933997 20.00 ug/1 -0.02 30) Phenanthrene-diO 25.58 188 1346867 20.00 ug/1 -0.03 39) Chrysene-dl2 33.64 240 849140 20.00 ug/1 -0.03 45) Perylene-dl2 37.87 264 548161 20.00 ug/1 -0.05

System Monitoring Compounds 2 8) TCMX 23.29 209 39678 8.48 ug/L -0.04 Spiked Amount 10.000 Recovery = 84.80% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.86 74 92596 9.44 ug/1 100 3) bis(2-Chloroethyl)ether 11.61 93 224645 14.71 ug/1 99 4) 1,3-Dichlorobenzene 12.11 146 234198 14.87 ug/1 100 5) 1,4-Dichlorobenzene 12.25 146 239149 15.09 ug/1 100 6) 1,2-Dichlorobenzene 12.77 146 229223 15.58 ug/1 98 7) 2,21-oxybis(1-Chloropropan 13.09 45 313783 14.87 ug/1 99 8) N-Nitroso-di-n-propylamine 13.47 70 138881 13.87 ug/1 99 9) Hexachloroethane 13.62 117 80529 13.87 ug/1 96 11) Nitrobenzene 13.89 77 195125 13.47 ug/1 98 12) Isophorone 14.54 82 330467 12.06 ug/1 97 13) bis(2-Chloroethoxy)methane 15.22 93 268782 15.06 ug/1 98 14) 1,2,4-Trichlorobenzene 15.73 180 201874 16.08 ug/1 99 15) Naphthalene 15.90 128 642670 16.18 ug/1 99 16) Hexachlorobutadiene 16.45 225 100041 15.93 ug/1 97 18) Hexachlorocyclopentadiene 18.64 237 13781 3.34 ug/1 95 19) 2-Chloronaphthalene 19.41 162 407407 16.54 ug/1 98 20) Dimethylphthalate 20.50 163 493414 17.37 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 93214 13.73 ug/1 97 22) Acenaphthylene 20.67 152 564990 16.40 ug/1 100 23) Acenaphthene 21.24 153 419008 17.10 ug/1 99 24) 2,4-Dinitrotoluene 21.87 165 112461 12.58 ug/1 100 25) Diethylphthalate 22.63 149 481423 17.67 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 236261 19.55 ug/1 97 27) Fluorene 22.76 166 475773 18.34 ug/1 97 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 418087 14.50 ug/L 98 31) N-Nitrosodiphenylamine 23.17 168 94616 8.45 ug/1 97 32) 4-Bromophenyl-phenylether 24.24 248 130989 20.03 ug/1 97

(#) = qualifier out of range (m) = manual integration REFA2.D GCMS0412.M Thu Apr 18 13:59:32 2002 Page 1

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