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GCMS analysis results for sample AE10809, May 2002

Machine-extracted title · confidence 50%

Gas chromatography-mass spectrometry report for sample AE10809 showing detection of unknown compounds and surrogate recovery.

NYC-WTC_000045984–000046005

Folder label: “GCMS X 5/7/02 A 5/15/02

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NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\1\DATA\051402\10809.D Vial : 19 Acq On : 15 May 2002 5:01 am Operator: Mclean Sample : 5/7 kb Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 4-Penten-2-one, 4-methyl- Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

7.73 0.30 ug/L 360644 1,4-Dichlorobenzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-3 27 2 3-Oxetanol, 2,2,3-trimethyl- 116 C6H1202 025910-96-7 25 3 3-Hexene-2,5-diol 116 C6H1202 007319-23-5 10 4 3-Pyrrolidinol 87 C4H9NO 040499-83-0 9 Abundance Scan 791 (7.727 min): 10809.D (-784) (-) m/z 43.10 100.00% 43

5000 58 87 ’ । l ■ 1 ■ ■ I ■ ■ ■ ■ । ■ ■ ■ ■ । 98 7.40 7.60 7.80 8.00 ol pT-TTp-FTTy?6.41 + 69 -PPH A l 49 i I I"1'I m/ z 58.10 28.76%

U m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #110033: 4-Penten-2-one, 4-methyl- 4(3

AywwWWir 5000 > I | | | i '। | r~1 I l pl l I [ > I i r |

7.40 7.60 7.80 8.00 28 83 m/z 87.10 24.24%

n/z-> 0 TI‘ .11,,1.739,a1. 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 55 1+I । II I I | I > I ! | i1 1" I" 111 m 98

Abundance #5761: 3-Oxetanol, 2,2,3-trimethyl- 43 ........................................... 1 1 | 1 1 "1| I I r i j i i i i j I i | | |

7.40 7.60 7.80 8.00 5000 m/z 41.20 14.10% 58 71 29 86 53 111 11 ■. 11 81,| 98 0 ......... ........ 'I""!,.!. TITHuTmT n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #5279: 3-Hexene-2,5-diol 43 7.40 7.60 7.80 8.00 m/ z 59.10 13.29%

5000 55 83 98 0 50 34.1. TH+ I I I I ] I i I । | r I i I ] I I r T । FTHT I I j I I I I I I I 1 I I I I I I I I I I I I I I I I I I I , 61 71 I | I I ! I | ! ! > ■ | I I । I | I ! I , | I ! ! ! | .....I -ip-T-T-r-Tp—r-r 1 1 1 ' 1 1 ' 1 1 ' ’ 1 I H...... , •n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 7.40 7.60 7.80 8.00

10809.D 050102.M Thu May 16 12:37:27 2002 Page 8

NYC-WTC_000045996

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