GCMS sample analysis results for AE10698, May 20 2002

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■ Data File : C:\MSDCHEM\1\DATA\020513\10698.D Vial: 9 Acq On : 13 May 2002 8:26 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 4 Heptasiloxane, 1,1,3,3,5,5,. Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T. 28.36 0.29 ug/1 28519 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Heptasiloxane, 1,1,3,3,5,5,7,7,9... 504 C14H4406Si7 019095-23-9 38 2 Benzoic acid, 2,4-bis[(trimethyl... 370 C16H3004Si3 010586-16-0 25 3 Phosphoric acid, 3-(ethoxyimino)... 429 C14H36NO6PSi3 055334-96-8 10 4 3-(2-Methoxyphenoxy)lactic acid,... 356 C16H2805Si2 1000072-00-0 9 Abundance Scan 4302 (28.356 min): 10698.D (-4292) (-) m/ z 73.10 100.00% 73

5000 147 355 A 1 A_______ A A A 221 281 1 1 ' 1 ' ' I' 11 1 1 11 ' 1 1 1 1 1 1 1 ' 401 28.00 28.20 28.40 28.60 43 I' 1 i 1 327 115 ' i ' ' 1 ' i ’ 'I. ' ' i ■ i I■ 1 ''' i 1 I 523 m/z 355.00 29.00% i 1 ‘ i ' ' ( ' I 1 * ■ ' I ■ - > > । ■ ■ ■ n/z—> 0 50 100 150 200 250 300 350 400 450 500 Abundance #27374: Heptasiloxane, 1,1,3,3,5,5,7,7,9,9,11,11,13,1 3-tet... 73

5000 207 1 n 1 । 1 ‘ ' 28.00 28.20 28.40 28.60 m/z 147.00 24.37% 133 281 355

n/z-> —6+ 0 50 . 103 I| 177, ■ ■ I 100 ■ ' 1 1 I ' 150 1 1 1 I 200 4 12531. r 11 r 250 300 327L [ 383 350 400 429 450 489 500 Abundance #115312: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trim... 73 AA-- 28.00 28.20 28.40 28.60 5000 355 m/z 221.00 22.15%

16 45

, . , 105 133,163 193 223 251 281 321 I k'n ' I 1 ' 1 1 I'' ' ' ' 1 ' ' 1 ■' I ' 1 ' 1 I 1 1 ' ■ । । ■ ■ । ।n । । i | । i । । | -i । r'i | i । m/z~> Abundance 0 50 73 100 150 200 250 300 350 400 450 #27799: Phosphoric acid, 3-(ethoxyimino)-2-[(trimethylsily... 299 500 ' 1T1 1 1 1 1 ' 28.00 28.20 28.40 28.60 L ‘■'T1 r

174 328 211 m/z 2 81.00 21.36% 384 5000 142 45 101 ,357 414

n/z—> 0 —

50 4 100 243 269 , y 4,4,8 r r ' 1 150 200 250 300 M.U. 350 400 450 r• ' ( 1 i 1 1 500 —

28.00 28.20 28.40 28.60

10698.D SCAN020507.M Wed May 15 08:33:46 2002 Page 6

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