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GCMS analysis results for unknown compounds, sample AE10200, May 2002

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Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE10200 on May 10, 2002.

NYC-WTC_000044942–000044958

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\10200.D Vial: 18 Acq On 9 May 2002 5:16 am Operator: Mclean Sample 4/30 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 4 Oxetane, 2,2-dimethyl- Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T.

7.73 0.23 ug/L 208260 1,4-Dichlorobenzene-d4 9.93 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Oxetane, 2,2-dimethyl- 86 C5H10O 006245-99-4 17 2 4-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-312 3 3-Pyrrolidinol 87 C4H9NO 040499-83-0 9 4 2-Propanone, 1-cyclopropyl-98 C6H10O 004160-75-2 9 Abundance Scan 792 (7.733 min): 10200.D (-787) (-) m/z 43.10 100.00% 43

5000 58 । । । । 1 1 i 1 1 1 1 i 1 1 1 1 i 1 1 1 ' i 38 । 51 83 87 98 7.40 7.60 7.80 8.00 0 i""I"1’I HH 1 | | I , I | I , I r I. |..... I I t I I I I I I I I I I I I pi।I|I।।ipni|iJipiiip. m/ z 58.10 24.76%

L /z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #4308: Oxetane, 2,2-dimethyl- 43 MMMMN" W AAMn 5000 56 ‘ 111’111’1 1ft" 1111 *‘ 1 28 7.40 7.60 7.80 8.00 m/z 87.10 14.69% 133 38 i I 50 11111111 Ol RR. 71 OQ | ( - /o 86। 0 I nip 1 11 +mt | | i t I | > I I I | I I । । | i r i i | ' i I I | I I I I | I I I ■ | I i i i | i i i i | i i

m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #110033: 4-Penten-2-one, 4-methyl- 43 ‘1111‘111 1*/1*/1"11‘*‘II 7.40 7.60 7.80 8.00 5000 m/z 55.00 13.24%

28 83 55 98

m/z-> —31 H 0 i ■ ■ ■11 - ■ r " ' i'' " i I | I ! I ! | I l n .ras , ! 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #4163: 3-Pyrrolidinol i ' 11 1 i 11 1 1 i 43 7.40 7.60 7.80 8.00 m/z 41.10 12.38% 5000 ) 57 68 87 ‘4 0 P11,p,iiplnp,,,piI,| +52+1— l4++77.,82 1111 p ,,,. । TTTT 111ITT m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 7.40 7.60 7.80 8.00

10200.D 050102.M Thu May 09 13:36:35 2002 Page 7

NYC-WTC_000044953

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