GCMS calibration data for volatile organics, sample AE10198, May 2002

NYC 9/11 Public Portal Document

r Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\050802\CAL50.D Vial: 2 Acq On 8 May 2002 11:52 am Operator: Mclean Sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 08 13:59:14 2002 Quant Results File: 050102.RES

Quant Method C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Last Update Wed May 08 09:53:56 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.93 152 4763876 40.00 ug/L 0.00 10) Napthalene-d8 13.43 136 19323695 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.57 164 10305401 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.95 188 15140159 40.00 ug/L 0.00 37) Chrysene-dl2 30.82 240 11374747 40.00 ug/L 0.01 43) Perylene-dl2 34.71 264 8351850 40.00 ug/L 0.00

System Monitoring Compounds 2 7) TCMX 20.54 209 746089 12.53 ug/L 0.00 Spiked Amount 10.000 Recovery = 125.30% 50) 2,4-ddd 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery . 00%

Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.82 74 4684457 47.99 ug/L 88 3) bis(2-Chloroethyl)ether 9.35 93 9311195 49.95 ug/L 89 4) 1,3-Dichlorobenzene 9.76 146 9046607 47.68 ug/L 99 5) 1,4-Dichlorobenzene 9.98 146 9821458 50.34 ug/L 98 6) 1,2-Dichlorobenzene 10.35 146 8716695 50.25 ug/1 99 7) 2,2‘oxybis(1-Chloropropane 10.81 45 14677579m 51.09 ug/L 8) N-nitroso-di-propylamine 11.14 70 6644447 50.28 ug/L 96 9) Hexachloroethane 11.25 117 3747258 52.08 ug/L 96 11) Nitrobenzene 11.50 77 9511793 50.88 ug/L 94 12) Isophorone 12.21 82 16978687 50.42 ug/L 98 13) bis(2-Chloroethoxy) methan 12.95 93 11212980 50.26 ug/L 98 14) 1,2,4-Trichlorobenzene 13.30 180 7168451 50.63 ug/L 99 15) Napthalene 13.49 128 25570111 49.39 ug/L 99 16) Hexachlorobutadiene 13.93 225 3385368 51.04 ug/L 98 18) 2-Chloronaphthalene 16.94 162 13355388 51.86 ug/L 98 19) Dimethylphthalate 18.02 163 16583762 49.56 ug/L 100 20) 2,6-Dinitrotoluene 18.13 165 2953420 52.49 ug/L 88 21) Acenapthylene 18.13 152 22824697 48.21 ug/L 97 22) Acenapthalene 18.67 153 14012594 51.91 ug/L 98 23) 2,4-Dinitrotoluene 19.28 165 3847583 51.35 ug/L 96 24) Diethylphthalate 20.15 149 14807018 51.11 ug/L 98 25) 4-Chlorophenyl-phenylether 20.34 204 7796219 51.81 ug/L 99 26) Fluorene 20.21 166 16352572 52.54 ug/L 97 28) Azobenzene 20.79 77 19465176 51.08 ug/L # 93 30) Nnitrosodiphenylamine 20.70 169 9238039 49.72 ug/L 94 31) 4-Bromophenyl-phenylether 21.77 248 3917833 52.39 ug/L 98 32) Hexachlorobenzene 21.80 284 3711089 51.84 ug/L 97 33) Phenanthrene 23.03 178 22782357 49.88 ug/L 98

(#) = qualifier out of range (m) = manual integration CAL50.D 050102.M Thu May 09 13:34:32 2002 Page 1

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