GCMS analysis results, sample AE09968, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050602\9968.D Vial: 25 Acq On 7 May 2002 7:14 am Operator: Mclean Sample 4/25 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 5,8,11-Heptadecatriynoic ac... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 34.88 0.39 ug/L 260714 Perylene-dl2 34.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 5,8,11-Heptadecatriynoic acid, m... 272 C18H2402 056554-57-5 9 2 3-Mercapto-5-ethyl-1,2,4-triazole 129 C4H7N3S 007271-45-6 5 3 Perylene-dl2 264 C20D12 001520-96-3 • 4 7,12a-Dimethyl-l,2,3,4,4a,11,12,... 264 C20H24 075758-27 •9 5 Abundance Scan 5412 (34.878 min): 9968.D (-5411) (-) m/z 129.50 100.00% 129

264 5000

207 34.60 34.80 35.00 35.20 44 73 i r [ i i i i । I i i i । i i ii । i r r • | > i i r । 1 11111 ■ ■ । ■ ■ ■11 ■1'11'11 ■ ।'1 ■11'11 I ■ TrI m/z 130.80 70.19% /z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #58427: 5,8,11-Heptadecatriynoic acid, methyl ester 129 141 41 — 91 115 155 5000 29 Til I I A < I ___________ A I I I ill I ] I I I I II 74 34.60 34.80 35.00 35.20 169 103 i l 183। 197 215 229 241 m/ z 128.10 65.66%

m/z-> 20 |l Jlulool444444r , ", , ll T—TTTTTTTTr 40 60 80 100 120 140 160 180 200 220 240 " 277,272 260 Abundance #58411: 3-Mercapto-5-ethyl-1,2,4-triazole 129

34 60 34.80 35.00 35.20 5000 m/z 264.10 52.05% 70

41 56 91 ........... i J., I, , Il 114 I I I I ' I I I I I ’ ’I I I ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ > ' ' I 1 । 1 I । । । 1 । । < । । i । ■ ।11 ‘11'11111 m/z->______ 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #95141: Perylene-d12 11।111'i71 ■ । । 1 1 ■ । । j ‘ 264 34.60 34.80 35.00 35.20 m/z 132.80 45.79% 5000

132 28 । ■ i ■ । । ■ ■ • ■ । 76 88 102 । । ■ 1 ■ > । 118 ............. 194 208 232 TTI ■11’1/7.1 i | i i r > | ■ 1 > । | I I I I | I I I I | I | ■ > I 1T0 .......... 1 1 i ' ■ 1 1 i ' TI /z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 34.60 34.80 35.00 35.20

9968.D 050102.M Tue May 07 15:47:03 2002 Page 13

NYC-WTC_000043955