GCMS reference results for volatile organics, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\APR0 4 0 5\REFAl.D Vial: 17 Acq On 6 Apr 2002 8:42 am Operator: Sample gc/ms scan 3/26 Inst : GC/MS 2 09 Mise Multiplr: 2.00 MS Integration Params: GOOFY.P Quant Time: Apr 15 14:24 2002 Quant Results File: GCMS0408.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0408.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Mon Apr 15 14:10:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0403

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 452663 20.00 ug/1 -0.01 10) Naphthalene-d8 15.89 136 1659750 20.00 ug/1 -0.02 17) Acenaphthene-diO 21.19 164 945447 20.00 ug/1 -0.01 30) Phenanthrene-diO 25.63 188 1335555 20.00 ug/1 -0.02 39) Chrysene-dl2 33.69 240 680167 20.00 ug/1 -0.03 45) Perylene-dl2 37.93 264 366756 20.00 ug/1 -0.02

System Monitoring Compounds 28) TCMX 23.33 209 29303 11.50 ug/mL 0.00 Spiked Amount 10.000 Recovery = 115.00% 38) 2,4-DDD 0.00 235 0 0.0 0 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.88 74 79807 13.04 ug/1 96 3) bis(2-Chloroethyl)ether 11.64 93 193515 19.49 ug/1 97 4) 1,3-Dichlorobenzene 12.14 146 164768 15.55 ug/1 99 5) 1,4-Dichlorobenzene 12.29 146 172393 16.18 ug/1 99 6) 1,2-Dichlorobenzene 12.81 146 169562 17.02 ug/1 98 7) 2,21-oxybis(1-Chloropropan 13.12 45 269251 20.28 ug/1 98 8) N-Nitroso-di-n-propylamine 13.51 70 128778 20.50 ug/1 97 9) Hexachloroethane 13.65 117 52995 _ 13.68 ug/1 98 11) Nitrobenzene 13.93 77 173639 18.55 ug/1 99 12) Isophorone 14.57 82 327732 18.79 ug/1 100 13) bis(2-Chloroethoxy)methane 15.25 93 235714 20.31 ug/1 99 14) 1,2,4-Trichlorobenzene 15.77 180 153682 17.77 ug/1 99 15) Naphthalene 15.94 128 513440 19.43 ug/1 99 16) Hexachlorobutadiene 16.48 225 62445 14.20 ug/1 100 18) Hexachlorocyclopentadiene 18.68 237 11802 3.88 ug/1 95 19) 2-Chloronaphthalene 19.45 162 321048 19.52 ug/1 98 20) Dimethylphthalate 20.53 163 417990 22.00 ug/1 100 21) 2,6-Dinitrotoluene 20.75 165 85562 19.09 ug/1 99 22) Acenaphthylene 20.71 152 476434 20.79 ug/1 99 23) Acenaphthene 21.28 153 344316 21.14 ug/1 99 24) 2z4-Dinitrotoluene 21.92 165 105263 18.34 ug/1 97 25) Diethylphthalate 22.66 . 149 402871 22.56 ug/1 100 26) 4-Chlorophenyl-phenylether 22.82 204 182505 22.06 ug/1 99 27) Fluorene 22.80 166 373908 21.57 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.28 77 338966 19.20 ug/L 99 31) N-Nitrosodiphenyl amine 23.21 168 126148 17.37 ug/1 98 32) 4-Bromophenyl-phenylether 24.29 248 96336 21.94 ug/1 96

(#) = qualifier out of range (m) = manual integration REFA1.D GCMS0408.M Mon Apr 15 14:26:28 2002 Page 1

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