GCMS DFTPP calibration pass report, April 12, 2002

NYC 9/11 Public Portal Document

Response Factor Report Instrumen

Method : C:\MSDCHEM\1\5973N\5080402BBC.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Apr 15 14:48:10 2002 Response via : Initial Calibration

Calibration Files 6 =C100A412.D 1 =C5A0412 . D 2 =C10A0412.D 3 =C25A0412.D 4 =C40A0412.D 5 =C80A0412.D

Compound 6 1 2 3 4 5 Avg %RSD

1) I 1,4-Dichlorobenzene-d ISTD 2) N-nitroso- dimet 1.190 1.022 1.095 1.128 1.265 1.240 1.157 7.98 3) bis(2-chloroeth 1.678 1.414 1.568 1.813 1.925 1.779 1.696 10.85 4) 1,3 Dichlorob 1.250 1.370 1.419 1.458 1.483 1.333 1.386 6.22 5) 1,4 Dichlorob 1.327 1.526 1.517 1.543 1.565 1.422 1.483 6.12 6) 1,2 Dichlorob 1.148 1.126 1.171 1.283 1.317 1.229 1.212 6.32 7) 2,2 1 - oxybis 2.145 2.564 2.641 2.662 2.713 2.456 2.530 8.26 8) N-Nitroso-di-n- 1.186 1.051 1.170 1.280 1.324 1.243 1.209 7.97 9) I Hexachloroethan 0.568 0.714 0.701 0.681 0.682 0.613 0.660 8.61

10) Naphthalene-d8 ----------------- ISTD------------------ 11) Nitrobenzene 0.411 0.281 0.326 0.432 0.449 0.430 0.388 17.62 12) Isophorone 0.711 0.738 0.758 0.833 0.834 0.759 0.772 6.54 13) bis (2-Chloroeth 0.451 0.427 0.428 0.512 0.527 0.482 0.471 9.00 14) 1,2,4-Trichloro 0.230 0.278 0.259 0.271 0.270 0.245 0.259 7.04 15) Naphthalene 0.821 1.078 1.039 1.030 1.013 0.889 0.978 10.25 16) Hexachlorobutad 0.113 0.129 0.122 0.131 0.132 0.121 0.125 5.67

17) Acenaphthene-dl0 ----------------- ISTD------------------- 18) Hexachlorocyclo 0.219 0.124 0.135 0.200 0.221 0.224 0.187 24.33/ 19) 2 -chloronaphtha 0.801 0.686 0.706 0.899 0.921 0.842 0.809 12.04 20) I Dimethylphthala 1.107 1.104 1.109 1.202 1.223 1.157 1.150 4.56 21) 2,6-Dinitrotolu 0.243 0.162 0.193 0.239 0.257 0.251 0.224 16.98 22) Acenaphthylene 1.372 1.431 1.457 1.569 1.577 1.469 1.479 5.41 23) Acenaphthene 0.798 1.016 0.992 0.986 0.972 0.850 0.936 9.53 24) 2,4-Dinitrotolu 0.317 0.191 0.235 0.266 0.297 0.314 0.270 18.34 25) Diethylphthalat 0.793 1.022 1.018 1.023 1.008 0.866 0.955 10.46 26) 4-Chlorophenyl- 0.472 0.550 0.537 0.558 0.555 0.497 0.528 6.68 27) Fluorene 0.896 1.157 1.164 1.156 1.130 0.974 1.079 10.69 28) s TCMX (SURR) 0.158 0.163 0.153 0.166 0.156 0.161 0.160 3.06 29) Azobenzen/ 1,2- 1.541 1.704 1.668 1.737 1.747 1.569 1.661 5.25

30) Phenanthrene-dl0 ----------------- ISTD------------------ 31) N-Nitrosodiphen 0.346 0.467 0.458 0.464 0.445 0.379 0.426 12.02 32) 4-Bromophenyl-p 0.172 0.180 0.184 0.191 0.201 0.182 0.185 5.45 33) Hexachlorobenze 0.157 0.180 0.177 0.177 0.182 0.165 0.173 5.51 34) Phenanthrene 0.947 1.210 1.183 1.150 1.150 1.011 1.108 9.44 35) Anthracene 0.997 1.166 1.187 1.182 1.185 1.067 1.131 7.08 36) Di-n-butylphtha 1.124 1.234 1.296 1.364 1.374 1.213 1.268 7.59 37) Fluoranthene 1.096 1.102 1.151 1.244 1.296 1.165 1.176 6.76 38) s 2,4-DDD (SURR) 0.256 0.285 0.347 0.299 0.311 0.289 0.298 10.11

39) Chrysene-dl2 ------------------------------- ISTD---------------------------------- 40) Pyrene 1.470 1.502 1.491 1.520 1.576 1.493 1.508 2.44 41) Butylbenzylphth 0.713 0.580 0.643 0.738 0.776 0.731 0.697 10.35 42) Benzo (a) antra 1.238 1.109 1.144 1.248 1.295 1.277 1.218 6.15 43) Bis (2-ethylhex 0.942 0.924 0.984 1.023 1.074 0.992 0.990 5.51 44) Chrysene 1.140 1.203 1.229 1.233 1.226 1.204 1.206 2.88

45) Perylene-dl2 ------------------------------- ISTD---------------------------------- 46) Di-n-Octylphtha 2.522 2.042 2.283 2.668 2.836 2.578 2.488 11.42 47) Benzo (b) fluor 1.541 1.346 1.482 1.602 1.680 1.594 1.541 7.53

(#) = Out of Range 5080402BBC.M Mon Apr 15 14:48:37 2002 Page 1

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