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GCMS analysis results, sample AE02148, March 2002

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Gas chromatography-mass spectrometry analysis of sample AE02148 conducted on 3/21/02, detecting unknown compounds and 2,4-DDD surrogate at 123 ug with MDL of 5.0 ug.

NYC-WTC_000038991–000038999

Folder label: “GCMS X 3/8/02 A 3/19/02

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NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\031802\2148.D Vial: 26 Acq On : 19 Mar 2002 10:37 pm Operator: McLean Sample : GC/MS SCAN 3/8 Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 02:21:51 2002 ।Quant Results File: 5080302.RES

Quant Method C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title Quantitation For Method 508gcscan Last Update Thu Mar 14 13:02:27 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 15 0 1538599 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 4263323 20.00 ug/L 0.00 17) Acenaphthene-diO 18.13 164 2330155 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3574397 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 3207887 20.00 ug/L -0.02 44) Perylene-dl2 34.18 264 1563517 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 262560 6.16 ug/L 0.00 Spiked Amount 5.000 Recovery = 123.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.28 74 18097 0.52 ug/L 100 3) bis(2-chloroethyl) ether 0.00 93 0 N.D. 4) 1,3 - Dichlorobenze 0.00 146 0 N.D. 5) 1,4 - Dichlorobenzene 0.00 146 0 N.D. 6) 1,2 - Dichlorobenzene 0.00 146 0 N.D. 7) 2,2 ‘ - oxybis (l-Chloropr 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy) methan 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 0.00 128 0 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 18.13 165 298216 11.04 ug/L # 25 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 0.00 149 0 N.D. 26) 4-Chlorophenyl-phenyl ethe 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 30) N-Nitrosodiphenylamine 0.00 169 0 N.D. 31) 4-Bromophenyl-phenyl ether 0.00 248 0 N.D. 32) Hexachlorobenzene 0.00 284 0 N.D. 3 3) Phenanthrene 0.00 178 0 N.D. 34) Anthracene 0.00 178 0 N.D. 35) Di-n-butylphthalate 24.65 149 5060 0.03 ug/L 79 36) Fluoranthene 0.00 202 0 N.D. 3 9) Pyrene 0.00 202 0 N.D. 40) Butylbenzylphthalate 0.00 149 0 N.D. 41) Benzo (a) antracene 0.00 228 0 N.D. d 42) Bis (2-ethylhexyl) phthala 43) Chrysene 45) Di-n-Octylphthalate 46) Benzo (b) fluoranthene 30.92 30.31 0.00 0.00 149 228 149 252 8126 7893 0 0 0.06 ug/L 0.05 ug/L N.D. N.D. 75

61 x (#) = qualifier out of range (m) = manual integration 2148.D 5080302.M Wed Mar 20 02:22:28 2002 Page 1

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