GCMS method 508 sample preparation log, March 22, 2002

NYC 9/11 Public Portal Document

$ Quantitation Report (QT Reviewed)

w Data File C:\HPCHEM\l\DATA\MAR2202\CAL40.D Vial: 2 Acq On 22 Mar 2002 5:08 pm Operator : Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 26 14:18 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue Mar 26 14:13:06 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.28 152 764332 20.00 ug/1 -0.07 10) Naphthalene-d8 15.92 136 3008344 20.00 ug/1 -0.08 17) Acenaphthene-diO 21.23 164 1646514 20.00 ug/1 -0.08 29) Phenanthrene-diO 25.68 188 2597804 20.00 ug/1 -0.08 3 8) Chrysene-dl2 33.75 240 1849417 20.00 ug/1 -0.09 44) Perylene-dl2 38.00 264 1135218 20.00 ug/1 -0.12

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.93 74 979871 37.79 ug/1 # 71 3) bis(2-Chloroethyl)ether 11.70 93 1554819 37.24 ug/1 90 4) 1,3-Dichlorobenzene 12.18 146 1671407 38.73 ug/1 100 5) 1,4-Dichlorobenzene 12.32 146 1677927 38.80 ug/1 99 6) 1,2-Dichlorobenzene 12.84 146 1560944 38.70 ug/1 100 7) 2,2' -oxybis (1-Chloropropan 13.16 45 2107308 35.86 ug/1 99 8) N-Nitroso-di-n-propylamine 13.58 70 1034333 38.07 ug/1 # 86 9) Hexachloroethane 13.68 117 623109 38.55 ug/1 96 11) Nitrobenzene 13.98 77 1526824 37.13 ug/1 93 12) 1sophorone 14.63 82 2895157 37.12 ug/1 100 13) bis(2-Chloroethoxy)methane 15.30 93 1908818 37.40 ug/1 98 14) 1,2,4-Trichlorobenzene 15.80 180 1396355 39.54 ug/1 97 15) Naphthalene 15.99 128 4322899 38.88 ug/1 99 16) Hexachlorobutadiene 16.51 225 714049 40.56 ug/1 100 18) Hexachlorocyclopentadiene 18.70 237 572997 51.38 ug/1 99 19) 2-Chloronaphthalene 19.49 162 2693064 38.09 1ug/1 96 20) Dimethylphthalate 20.59 163 3181925 38.41 ug/1 100 21) 2,6-Dinitrotoluene 20.81 165 776170 38.59 ug/1 # 82 22) Acenaphthylene 20.76 152 3841759 38.01 ug/1 99 2 3) Acenaphthene 21.33 153 2682803 37.98 ug/1 98 24) 2,4-Dinitrotoluene 21.98 165 1017007 37.80 ug/1 # 75 25) Diethylphthalate 22.73 149 3014058 37.47 ug/1 96 26) 4-Chlorophenyl-phenylether 22.86 204 1351657 39.24 ug/1 94 27) Fluorene 22.85 166 2847116 38.11 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.34 77 2939199 34.09 ug/L # 85

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS0308.M Tue Mar 26 14:18:46 2002 Page 1

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