GCMS analysis comments for sample AD29518 with phthalate detection, Jan

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC1301\29463.D Vial: 11 Acq On : 13 Dec 2001 7:38 pm Operator: 209 GALOS Sample : gems scan 12/6 Inst : GC/MS- 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanol, 1-(2-methoxy-l-met Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

11.33 1.83 ug/1 682642 1,4-Dichlorobenzene-d4 11.67

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanol, 1-(2-methoxy-1-methylet 148 C7H16O3 020324-32-7 90 2 2-Butanol, 3,3-oxybis- 162 C8H18O3 054305-61-2 64 3 2-Propanol, 1-(2-methoxypropoxy)- 148 C7H16O3 013429-07-7 50

Al 4 1-Propanol,/z-(2-hydroxypropoxy)- 134 C6H14O3 000106-62-7 42 Abundance Scan 685 (11.331 min): 29463.D (-) m/ z 59.05 100.00% 59

5000- 45 103 73 11.00 11.20 11.40 11.60

miz-> -- 20 30 40 —5053— 60 TI 70 80 90 100 110 120 85 91 । ........ 130.... 130 140 m/ z 44.95 44.73% Abundance #9238: 2-Propanol, 1-(2-methoxy-1-methylethoxy)- 59

5000 103 ■ । ■ ■ ■ ' । 45 11.00 11.2G 11.40 11.60 73 31 m/z 103.05 33.82% ........... - ■ i ■ ■ ■ ' I ' ■ ' ■ i 1 ' ' ■ i ' ■ ■ ■ i ' ,......... 130.... miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #12859: 2-Butanol, 3,3‘-oxybis- 59 ■ ■ । ■ 1 i • 11.00 11.20 11.40 11.60 m/ z 73.0.00 26.44%

N 5000- 31 45 103 l

, i .I i 1 _____ 134 ■ t ■ ■ • 1 1 ■ i ■ 1 ■ ■ i ' ■ ■ ■ I ■ ' ■ ' i ' ■ ■ ■ i ' ■ ' ■ i ■ ■ ■ ' i ■ ■ ■ ■ i ■ ■ ■ ■ i '

m/z—> 20 3G 40 50 60 70 80 90 100 110 120 130 140 Abundance #9233: 2-Propanol, 1-(2-methoxypropoxy)- 59 11.00 11.20 11.40 11.60 m/ z 41.00 23.22%

NN 5000-

31 45 ..... | ■ i ■ ■ ■ ■ i ■ 73 ■ i 1 ■ ■ ■ I ■ ■ ■ ‘ i ■ ■ ' ■ 104 i ' 1 ' ' i ' ■ ' ' i ' 130 ' ■ ' i ■ ' ‘ ' i 1 1II ■ । ■ ■ ■ • ।

m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 11.00 11.20 11.40 11.60

29463.D GCMS1126.M Fri Dec 21 13:08:13 2001 Page. 2

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