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GCMS analysis results for sample AD28104, Jan 2002

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Laboratory report documenting GCMS analysis of sample AD28104 conducted on January 2, 2002.

NYC-WTC_000034615–000034630

Folder label: “GCMS X 11/23/01 A 12/21/01

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NYC 9/11 Public Portal Document Library Search Compound Report t Data File : C: \HPCHEM\ 1\DATA\DEC2101\28167.D Vial: 17 Acq On : 22 Dec 2001 9:25 am Operator: GALOS Sample : gems unknown 11/23 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.75 4.17 ng/uL 915618 1,4-Dichlorobenzene-d4 11.78

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2 -Pentanone ,/4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 43 2 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 43 3 5-Hexen-2-one 98 C6H10O 000109-49-9 9 4 3 -Hydro: -2-pentanone 102 C5H10O2 003142-66-3 9 (Abundance Scan 317 (7.749 min): 28167.D (-) m/ z 43.10 100.00% 43

5000 59

—PPPT, TT 101 • i ■ ■ ■ 1 1 ■ _ 7 40 7.60 7.80 8.00 8.20 , 38 +53+ ' ' i 1 1 1 1 i 1 ' ' 1T.1.—T.T T ( 83 —PPTT TIT TTT i r TT — m/z 59.10 49.25% miz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 43 — TTTTTTTT I T 5000 59 7.40 7.60 7.80 8.00 8.20 m/z 101.05 16.66% 27 _____ . I_______ , . 49 ________ 83 101 i ■ ' ' ■ i ■ ■ ■ ■ I Tr 1 TT 1 1 ■ ' T ■ ■ ' i ■ 1 1 1 I T 1 1 I 1 1 1 ' I ' ' 1 ■ i ' ■ ■ ■ i ■ mz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #3245,2 Peptanone, 4-hyorxyd-methyl- I 43 TTTPTTIDITT TTIETImIT 7.40 7.60 7.80 8.00 8.20 5000 59 m/ z 58.10 15.86%

I 31 73 83 101 : —IIIT mfe->_____ 10____ 20 30 40____ 50 ...... 60 70 ___80 90 100 110 Abundance #63205: 5-Hexen-2-one TT-p-m J > t | ' i > ■ ) । ■ i ■ । < 1 4b 7.40 7.60 7.80 8.00 8.20 m/z 41.10 7.39% 5000

55 15 27 83 98 ....... i ........|........ 38 ; . 50 ' 1 1 1 1 ' • I 1 1 1 1 1 1 1 ' 1 1 1 1 ' 1 1 1 ' 1 1 । ' 1 1 ■ i Tr TTT 1,1 TTTTTTTT 1 ' I Pr l. r TI T , IAT miz-> 10 20 30 40 50 60 7G 80 90 100 110 7.40 7.60 7.80 8.00 8.20

28167.D NP112701.M Fri Dec 28 09:58:09 2001 Page 4

NYC-WTC_000034626

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NYC-WTC_000034626Source: NYC Law Department, mirrored locally

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