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GCMS comments for sample AD28325, Nov 2001

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Analytical commentary for sample AD28325 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

NYC-WTC_000033816–000033824

Folder label: “GCMS X 11/20/01 A 11/26/01

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NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\NOV2 601\28325.D Vial: 14 Acq On : 28 Nov 2001 5:59 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Nov 28 9:24 2001 Quant Results File: GCMS1126.RES Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue Nov 27 12:20:14 2001 Response via : Initial Calibration DataAcq Meth : NP103001

Compound R.T. Qlon Response Cone Unit Qvalue 33) Acenaphthylene 0.00 152 0 N.D. 3 4) Acenaphthene 0.00 153 0 N.D. 35) 2,4-Dinitrophenol 0.00 184 0 N.D. 36) 4-Nitrophenol 0.00 65 0 N.D. 37) 2,4-Dinitrotoluene 20.85 165 1450/ N.D. 38) Diethylphthalate 22.09 149 1125 / N.D. 39) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 40) Fluorene 0.00 166 — 0 N.D. 41) Azobenzen/ 1,2-Diphenylhyd 22.73 77 105. N.D. 43) 4,6-Dinitro-.2-methylphenol 0.00 198 N.D. 44) N-Nitrosodiphenylamine 0.00 168 0 N.D. 45) 4-Bromophenyl-phenylether 0.00 248 0 N.D. 46) Hexachlorobenzene 0.00 284 0 N.D. 47) Pentachlorophenol 0.00 266 0 N.D. 48) Phenanthrene 24.99 178 842 / N.D. 49) Anthracene 24.99 178 842 ' N.D. 50) Di-n-butylphthalate 27.00 149 3187 / N.D. 51) Fluoranthene 0.00 202 0 N.D. 54) Pyrene 0.00 202 0 N.D. 55) Butylbenzylphthalate 0.00 149 0 N.D. 5 6) Benzo(a)anthracene 33.02 228 2859/ N.D. 57) Bis(2-ethylhexyl)phthalate 33.30 149 1688 / N.D. 58) Chrysene 33.02 228 2859 / N.D. 60) Di-n-Octylphthalate 35.06 149 N.D. 61) Benzo(b)fluoranthene 36.07 252 N.D. 62) Benzo(k)fluoranthene 36.07 252 3 N.D. 63) Benzo(a)pyrene 37.12 252 2373 N.D. 64) Indeno(1,2,3-cd)pyrene 0.00 276 0 N.D. 65) Dibenz(a,h)anthracene 0.00 278 0 N.D. 66) Benzo(g,h,i)perylene 0.00 276 0 N.D.

(#) = qualifier out of range (m) = manual integration 28325.D GCMS1126.M Wed Nov 28 09:46:25 2001 Page 2

NYC-WTC_000033819

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NYC-WTC_000033819Source: NYC Law Department, mirrored locally

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Analytical commentary for sample AD28265 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

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