GCMS calibration table for TCLP analysis, Dec 2001

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\DEC1201\LB.D Vial: 2 Acq On : 12 Dec 2001 4:13 pm 0)632-4 Operator: GALOS Sample : gc/ms unknown 11/14 02 4 Inst : GC/MS Ins Misc : MS Integration Params: RTEINT.P —P202/7 Multiplr: 1.00

Quant Time: Dec 14 9:16 2001 2029-00 Quant Results File: NP112701.RES 138-99 22%5o— Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Last Update : Wed Nov 28 15:33:44 2001 Response via : Initial Calibration DataAcq Meth : NP112701

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.84 152 1324056 20.00 ng/uL -0.10 19) Naphthalene-d8 15.44 136 5190730 20.00 ng/uL -0.11 31) Acenaphthene-diO 20.71 164 2290478 20.00 ng/uL -0.11 49) Phenanthrene-diO 25.12 188 3449662m 20.00 ng/uL -0.12 59) Chrysene-dl2 33.13 240 2219887 20.00 ng/uL -0.12 68) Perylene-dl2 37.21 264 1609473 20.00 ng/uL -0.13

System Monitoring Compounds 4) 2-Fluorophenol 0.00 112 0 0.00 ng/uL Spiked Amount 75.000 Range 18 42 Recovery = 0.00%# 5) Phenol-d5 0.00 99 0 0.00 ng/uL Spiked Amount 75.000 Range 19 32 Recovery = 0.00%# 6) 2-Chlorophenol-d4 11.84 132 1560 0.02 ng/uL 0.41 Spiked Amount 75.000 Range 34 84 Recovery = 0.03%# 7) 1,2-Dichlorobenzene-d4 12.07 152 293 0.01 ng/uL -0.39 Spiked Amount 50.000 Range 26 73 Recovery = 0.02%# 20) Nitrobenzene-d5 0.00 82 0 0.00 ng/uL Spiked Amount 50.000 Range 55 98 Recovery = 0.00%# 32) 2-Fluorobiphenyl 18.87 172 2341 0.02 ng/uL 0.04 Spiked Amount 50.000 Range 42 78 Recovery = 0.04%# 33) 2,4,6-Tribromophenol 0.00 330 0 0.00 ng/uL Spiked Amount 75.000 Range 45 96 Recovery = 0.00%# 62) Terphenyl-dl 4 0.00 244 0 0.00 ng/uL Spiked Amount 50.000 Range 58 98 Recovery = 0.00%#

Target Compounds Qvalue 2) Pyridine 0.00 79 0 N.D. 3) N-nitrosodimethylamine 0.00 74 0 N.D. 8) Phenol 0.00 94 0 N.D. 9) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 10) 2-Chlorophenol 0.00 128 0 N.D. 11) 1,3-Dichlorobenzene 0.00 146 0 N.D. 12) 1,4-Dichlorobenzene 0.00 146 0 N.D. 13) 1,2-Dichlorobenzene 0.00 146 0 N.D. 14) 2-Methylphenol 0.00 108 0 N.D. 15) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 16) 3&4-Methylphenol 0.00 108 0 N.D.

(#) = qualifier out of range (m) = manual integration LB.D NP112701.M Fri Dec 14 12:18:26 2001 Page 1

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