VOC analysis results, sample AE03507, Feb 22 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\02feb22\0222C10.D Vial: 2 Acq On : 22 Feb 2002 10:32 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 22 11:11 2002 Quant Results File: HP021702.RES Quant Method : C:\HPCHEM\1\METHODS\HP021702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Feb 19 16:16:43 2002 Response via : Initial Calibration DataAcq Meth : HP021702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.12 114 2585687 5.00 ug/L 0.00 24) CHLOROBENZENE-D5 21.79 117 2496667 5.00 ug/L 0.03 52) 1,4-DICHLOROBENZENE-D4 26.97 152 1279492 5.00 ug/L 0.02

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.37 65 851536 4.33 ug/L 0.02 Spiked Amount 5.000 Recovery = 86.60% 3) 4-BROMOFLUOROBENZENE 24.36 174 948482 4.88 ug/L 0.01 Spiked Amount 5.000 Recovery = 97.60% 25) TOLUENE-D8 18.49 98 3190570 5.15 ug/L 0.02 Spiked Amount 5.000 Recovery = 103.00% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.89 85 826900 9.08 ug/L 97 5) CHLOROMETHANE 5.51 50 717250 10.34 ug/L 99 6) VINYL CHLORIDE 5.62 62 377347 10.65 ug/L 96 7) BROMOMETHANE 6.61 94 488309 11.59 ug/L 97 8) CHLOROETHANE 6.75 64 413946 9.73 ug/L 98 9) TRICHLOROFLUOROMETHANE 7.30 101 930325 11.39 ug/L 98 12) ACETONE 8.28 43 132699 7.47 ug/L 95 13) 1,1-DICHLOROETHENE 8.63 61 1369626 11.02 ug/L 97 14) METHYLENE CHLORIDE 9.64 49 1470613 9.85 ug/L 98 15) METHYL TERT BUTYL ETHER 9.94 73 1418996 8.60 ug/L 95 16) TRANS-1,2-DICHLOROETHENE 10.30 61 1588504 9.99 ug/L 99 17) 1,1-DICHLOROETHANE 11.20 63 1885460 10.04 ug/L 98 18) 2-BUTANONE (MEK) 12.02 43 265076 6.44 ug/L< 99 19) 2,2-DICHLOROPROPANE 12.41 77 1395217 9.26 ug/L 95 20) CIS-1,2-DICHLOROETHENE 12.52 96 1160532 10.82 ug/L 94 21) CHLOROFORM 12.84 83 1882100 9.97 ug/L 100 22) BROMOCHLOROMETHANE 13.21 49 933227 10.40 ug/L 96 23) 1,2-DICHLOROETHANE 14.56 62 1159056 9.13 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.74 97 1408126 10.11 ug/L 97 27) 1,1-DICHLOROPROPENE 14.06 75 1483699 10.68 ug/L 96 28) CARBON TETRACHLORIDE 14.32 117 1192527 10.54 ug/L 98 29) BENZENE 14.66 78 3931358 10.90 ug/L 100 30) TRICHLOROETHENE 15.94 95 1189350 11.03 ug/L 92 31) 1,2-DICHLOROPROPANE 16.30 63 1089539 10.69 ug/L 95 32) DIBROMOMETHANE 16.96 174 531540 10.98 ug/L 98 33) BROMODICHLOROMETHANE 16.81 83 1338316 10.26 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.28 63 374012 9.92 ug/L 96 35) METHYL ISO-BUTYL KETONE 17.37 58 192850 10.33 ug/L 91 36) CIS-1,3-DICHLOROPROPENE 17.90 75 1520153 10.57 ug/L 99 37) TOLUENE 18.66 91 4306212 11.42 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.93 75 1068386 10.14 ug/L 97 39) 1,1,2-TRICHLOROETHANE 19.33 97 676276 11.07 ug/L 98 40) TETRACHLOROETHENE 20.11 166 1227475 11.96 ug/L 98 41) 1,3-DICHLOROPROPANE 19.85 76 1259191 10.52 ug/L 99 42) DIBROMOCHLOROMETHANE 20.53 129 817328 11.12 ug/L 97 43) 1,2-DIBROMOETHANE 20.99 107 692959 10.47 ug/L 93 44) CHLOROBENZENE 21.88 112 2847893 11.84 ug/L 94 45) 1,1,1,2-TETRACHLOROETHANE 21.91 131 938440 11.64 ug/L 97 46) 2-HEXANONE 19.21 43 357602 9.54 ug/L 96 47) ETHYLBENZENE 21.91 91 4975222 11.45 ug/L 96 48) P & M-XYLENE 22.07 106 3504666 23.64 ug/L 93 (#) = qualifier out of range (m) = manual integration 0222C10.D HP021702.M Fri Feb 22 11:11:31 2002 Page 1

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