VOC analysis results, sample AE02089, Feb 7 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\1\DATA\02 febO 6\02 06R5.D Vial: 3 Acq On 6 Feb 2002 2:59 pm Operator: 201-wb Sample ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Feb 6 15:37 2002 Quant Results File: HP013102.RES_

Quant Method : C:\HPCHEM\1\METHODS\HP013102.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Fri Feb 01 13:18:32 2002 -utus Response via : Initial Calibration DataAcq Meth : HP013102

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.10 114 2200439 5.00 ug/L -0.02 24) CHLOROBENZENE-D5 21.74 117 2159086 5.00 ug/L -0.02 52) 1,4-DICHLOROBENZENE-D4 26.93 152 1044231 5.00 ug/L -0.02

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.33 65 832853 4.37 ug/L -0.02 Spiked Amount 5.000 Recovery = 87.40% 3) 4-BROMOFLUOROBENZENE 24.34 174 822128 4.87 ug/L -0.02 Spiked Amount 5.000 Recovery = 97.40% 25) TOLUENE-D8 18.45 98 2718199 5.04 ug/L -0.02 Spiked Amount 5.000 Recovery = 100.80%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.86 85 248950 6.62 ug/L 100 5) CHLOROMETHANE 5.47 50 256939 5.87 ug/L 99 6) VINYL CHLORIDE 5.59 62 123774 4.76 ug/L 97 7) BROMOMETHANE 6.59 94 147367 4.60 ug/L 100 8) CHLOROETHANE 6.73 64 145427 5.15 ug/L 98 - 9) TRICHLOROFLUOROMETHANE 7.28 101 295070 4.46 ug/L 99 10) Isopropyl Alcohol 7.87 45 5366 47.02 ug/L 63 12) ACETONE 8.25 43 96274 8.11 ug/L 89 13) 1,1-DICHLOROETHENE 8.60 61 423222 4.09 ug/L 14) METHYLENE CHLORIDE 15) METHYL TERT BUTYL ETHER 9.61 9.91 49 73 581930 521380 5.69 ug/L 4.05 ug/L ,199 10836 16) TRANS-1,2-DICHLOROETHENE 10.27 61 541653 4.32 ug/L 1 96 17) 1,1-DICHLOROETHANE 11.16 63 655289 4.34 ug/L 18) 2-BUTANONE (MEK) 12.00 43 256408 9.19 ug/L 19) 2,2-DICHLOROPROPANE 12.38 77 547324 4.33 ug/L - 4. IS 99 20) CIS-1,2-DICHLOROETHENE 12.48 96 389654 4.31 ug/L " 98 21) CHLOROFORM 12.82 83 699687 4.16 ug/L 99 22) BROMOCHLOROMETHANE 13.18 49 320356 4.42 ug/L 90 23) 1,2-DICHLOROETHANE 14.54 62 478866 4.04 ug/L 97 — 26) 1,1,1-TRICHLOROETHANE 13.70 97 538775 3.94 ug/L 98 27) 1,1-DICHLOROPROPENE 28) CARBON TETRACHLORIDE 14.03 14.29 75 117 550071 436854 34.50 ug g .92 uq/L_ 99 99 29) BENZENE 30) TRICHLOROETHENE 14.63 15.90 78 95 1394057 435863 4.63 ug/ 4.35 ug/L 100 96 31) 1,2-DICHLOROPROPANE 16.26 63 401416 4.56 ug/L 99 — 32) DIBROMOMETHANE 16.92 174 188.516 4.01 ug/L 97 — -muae 33) BROMODICHLOROMETHANE 16.78 83 511399 3.86 ug/L 99 — 34) 2-CHLOROETHYL VINYL ETHER 17.25 63 134884 3.60 ug/L 95 —

(#) = qualifier out of range (m) = manual integration 0206R5.D HP013102.M Wed Feb 06 15:37:34 2002 Page 1

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