VOC analysis results, sample AE02089, Feb 7 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\02feb06\2384.D Vial: 12 Acq On 7 Feb 2002 2:38 am Operator: 201-wb Sample nyc Inst : GC/MS Ins _ Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\HP013102.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 1,3,5-Cycloheptatriene Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

18.65 0.02 ug/L 31665 CHLOROBENZENE-D5 21.78

Hit# of 5 Tentative ID MW MolForm CAS# Qual _ 1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 4 9 2 Cyclobutene, 2-propenylidene- 92 C7H8 052097-85-5 4 3 Bicyclo[3.2.0]hepta-2,6-diene 92 C7H8 002422-86-8 4 4 Spiro[3.3]hepta-1,5-diene 92 C7H8 022635-78-5 2 Abundance Scan 848 (18.646 min): 2384.D (-) m/z 91.10 100.00% 91

5000 39 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ' ■ ■ ■ i • ■

44 18.40 18.60 18.80 19.00 1 ■ i'n' i ■ “ ‘ i ■ ■ ■ ■ i" )) ■ ■ i “ ■ ■ i ■ ■ m/z 92.10 54.91% mlz-> 20253035404550556065 70 75 80859095 100 Abundance #63036:1,3,5-Cycloheptatriene SI

5000 ■ ■ I ' ■ ■ ■ i ■ • ■ i ■ ■ ■ ■ i ■ ■ 18.40 18.60 18.80 19.00 65 m/ z 38.85 26.17% 27 38 miz-> THTTTHTT ■11 ■ ,46.71—614— ■ i' ■ ■' i " ' ■ i11 “ i'' ■11 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #964: Cyclobutene, 2-propenylidene- SI -oooime i

18.40 18.60 18.80 19.00 5000 m/z 43.95 17.27%

65 51 . 77 TTTTTTLTTTTLTTTTETTTIWTTTTTTTHTT 1161, 11111 pi, । • i•i • • ■ ■ i■ ■' *i"■11 Paapur niz-> 2025303540455055 60 65 70 75 80 85 90 95 100 Abundance #966: Bicyclo[3.2.0]hepta-2,6-diene S1 18.40 18.60 18.80 19.00 m/z40.05 11.27%

5000

39 66

m/z—> 171... 10.5....... H.... .20...25273035404550556065 pn...... 70 75 808590 95 100 18.40 18.60 18.80 19.00

2384.D HP013102.M Thu Feb 07 03:18:00 2002 Page 5

NYC-WTC_000019543