SB1524 volatile analysis results, sample AE01938, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\02FEB04\01942F.D Vial: 14 Acq On 4 Feb 2002 7:52 pm Operator: 201-wb Sample : nyc fb Inst : GC/MS Ins Mise : February 4, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\HP013102.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Library : C:\DATABASE\NBS75K.L ********************************** k* ********************************* Peak Number 5 Butanoic acid, methyl ester Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

16.57 0.06 ug/L 56527 1,4-DIFLUOROBENZENE 15.15

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butanoic acid, methyl ester 102 C5H10O2 000623-42-7 50 2 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 9 3 3-Pyrrolidinol 87 C4H9NO 040499-83-0 9 4 Oxirane, butyl- 100 C6H120 001436-34-6 9 Abundance Scan 728 (16.575 min): 01942F.D (-) m/ z 43.05 100.00% 43 74

5000 59 87 • i ' 1 1 ■ 1 1 16.20 16.40 16.60 16.80 17.00 1 * । * * * * । ■ ■ 1 ■ । 1 * > 1 । ■ ' i ■ ■ ‘ ■ i ' 1 1 i ■ ■ ■ ■ i ■ ' ■ ■ । ‘ । m/z 74.05 83.45% iz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #63493: Butanoic acid, methyl ester 4 74

5000 27 16,20 16,40 16,60 16.80 17.00 15 59 m/z 68.65% 87 '............................ 33 102 "I l'.............. ) —dt ' ' i ■ ■ ■ ■ i ■ ■ 1 ■ i ' ■ i

niz—> 10 20 30 40 50 60 70 80 90 100 110 Abundance #763:1-Butanamine, 3-methyl- 33 ■ i • ■ • ■ i ■ ■ ■ ■ i 1 16.20 16.40 16.60 16.80 17.00 5000 m/z 52.61%

15 L ' 1 1 41 55 70 87 I 1 1 I ‘ 1 i ' ■ ■ 1 I ■'1 1-1 ! 1 1 ''' I 1 1 1 1 I 1 ' ' ' I miz—> 10 20 30 40 50 60 70 80 90 100 110 Abundance #752: 3-Pyrrolidinol 1 i 1 ' ■ ■ i ■ ■ ■ 1 i ■ 43 16.20 16.40 16.60 16.80 17.00 m/z 39.05 42.55%

5000-

87 57 68 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ r ' ‘ 1 1 1 1 1 I ‘ 1 1 1 1 * 1 1 1 1 ' — — mz—> 10 20 30 40 50 60 70 80 90 100 110 16.20 16,40 16.60 16.80 17.00

01942F.D HP013102.M Tue Feb 05 09:50:37 2002 Page 5

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