SB1524 volatile analysis results, sample AEO1636, Jan 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\l\DATA\02JAN31\1637.D Vial: 18 Acq On : 31 Jan 2002 10:08 pm Operator: 206-bh Sample : nyc Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\HP013102.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Titanium, [ (1,2,3-.eta.)-2-but Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T. 5.13 0.48 ug/L 43335 1,4-DIFLUOROBENZENE 14.41 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Titanium, [(1,2,3-.eta.)-2-butenyl] 207 C12H15T1 039015-02-6 83 2 (4Z)-5-Chloro-3,4-dimethyl-2,4-hept 158 C9H15C1 000000-00-0 83 3 Propanenitrile, 3-chloro- 89 C3H4C1N 000542-76-7 74 4 2,4-Hexadiyne 78 C6H6 002809-69-0 74 Abundance Scan 125 (5,126 min): 1637.D (-) m/z 49.10 100.00% 43 8000 63 207 78 6000

4000 94 ' ‘ i ■ ■ ■ • i ‘ ■ i 1 1 1 ' i ■ ■ ■ ■ i 4.80 5.00 5.20 5.40 — ‘ I ■' ,-l“ “I i1 ■ *' i T 11111112211027‘1‘E71""T‘O‘BBTE‘2‘1‘"111 m/z 45.0.0 78.42% nz-> 2030405060 70 8090 100110120130140150160170180190200210 Abundance #24592: Titanium, [(1,2,3-.eta.)-2-birtenyl](.eta.8-1,3,5,7- 73 104 152 207 39 8000

6000 4000 48 113 126 ‘ ' i ' ' ‘ ‘ i ' ■ 4.80 m/z 5.00 63.10 a. A 5.20 5.40 69.90% 20004 ‘ I • ‘• l “ • • I»“ ■ i" ■ ■ i ■1 ■ p-n-rp-rn-p- Tym-rpT TT-TTT9otttyott10223733333 miz-> 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #11920: (4Z)-5-Chloro-3,4-dimethyl-2,4-heptadiene 33 • 4 i ‘ ‘ ‘ 1 i * 1 * • i * ‘ • i 4.80 5.00 5.20 5.40 51 77 5000 107 m/z 207.10 66.92% 65

miz-> Abundance -1»> <«i«• • • i <«• ‘ i

49 ‘ 1111 Ji. 1111, । 95 1 123 " i ’ 1141 “ “ i 2030405060 70 8090 100110120130140150160170180190200210 I

#863: Propanenitrile, 3-chloro- 158

_DAAa 4.80 m/z 5.00 78.10 5.20 5.40 65.35%

No 5000 89 26 35 Tfm IUB199071T1 61 T m ।.. 111।... .|.... ।.... ।.... ।.... ।.... ।.... j... NJAMM) miz—> 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 4.80 5.00 5.20 5.40

1637.D MDLVOA.M Tue Feb 19 16:47:52 2002 Page 1

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