GCMS calibration results for volatile organics, Dec 2001

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\DEC1901\CAL25.D Vial: 2 Acq On 19 Dec 2001 10:40 am Operator: 209 GALOS Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Dec 19 11:28 2001 Quant Results File: NP091101.RES

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Last Update ’: Fri Oct 12 09:04:47 2001 Response via : Initial Calibration DataAcq Meth : NP091101

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.68 152 1087425 20.00 ug/1 -0.23 19) Naphthalene-d8 15.29 136 4175600 20.00 ug/1 -0.24 31) Acenaphthene-diO 20.56 164 2060568 20.00 ug/1 -0.26 49) Phenanthrene-diO 24.98 188 3067579 20.00 ug/1 -0.26 59) Chrysene-dl2 33.02 240 2174404 20.00 ug/1 -0.26 68) Perylene-dl2 37.12 264 1528630 20.00 ug/1 -0.30

System Monitoring Compounds 4) 2-Fluorophenol 8.52 112 5522001 ।69.29 ug/1 -0.22 Spiked Amount 75.000 Recovery 92.39% 5) Phenol-d5 10.92 99 6851292 78.43 ug/1 -0.22 Spiked Amount 75.000 Recovery = 104.57% 6) 2-Chlorophenol-d4 11.17 132 5403762 65.77 ug/1 -0.24 Spiked Amount 75.000 Recovery = 87.69% 7) 1,2-Dichlorobenzene-d4 12.19 152 2304614 43.44 ug/1 -0.24 Spiked Amount 50.000 Recovery = 86.88% 20) Nitrobenzene-d5 13.31 82 3781214 53.51 ug/1 -0.23 Spiked Amount 50.000 Recovery = 107.02% 32) 2-Fluorobiphenyl 18.57 172 6078569 43.67 ug/1 -0.24 Spiked Amount 50.000 Recovery = 87.34% 33) 2,4,6-Tribromophenol 22.99 330 1198459 66.14 ug/1 -0.25 Spiked Amount 75.000 Recovery = 88.19% 62) Terphenyl-dl4 29.90 244 5191696 39.61 ug/1 -0.25 Spiked Amount 50.000 Recovery = 79.22%

Target Compounds Qvalue 2) Pyridine 5.33 79 1386311 15.75 ug/l # 90 3) N-nitroso-dimethyl amine 5.40 74 1313883 25.04 ug/1 81 8) Phenol 10.95 94 2607998 26.03 ug/1 98 9) bis(2-Chloroethyl)ether 11.11 93 2011124 26.33 ug/1 99 10) 2-Chlorophenol 11.21 128 1830976 23.64 ug/1 95 11) 1,3-Dichlorobenzene 11.58 146 1948737 23.19 ug/1 99 12) 1,4-Dichlorobenzene 11.73 146 1965861 23.23 ug/1 99 13) 1,2-Dichlorobenzene 12.23 146 1818683 23.23 ug/1 99 14) 2-Methylphenol 12.52 108 1716465 25.57 ug/1 97 15) 2,2'-oxybis(1-Chioropropan 12.57 45 2942225 27.24 ug/1 97 16) 3&4-Methylphenol 12.94 108 1769954 25.81 ug/1 # 97

(#) = qualifier out of range (m) = manual integration CAL25.D GCMS1126.M Thu Jan 03 09:58:46 2002 Page 1

NYC-WTC_000016690