GCMS reference standard results for organic compounds, February 2002

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Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\JAN1502\REFA.D Vial: 6 Acq On : 15 Jan 2002 2:50 pm Operator: 209 GALOS Sample : gc/ms scan 12/26 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 4 12:48 2002 ’Quant Results File: GCMS1126.RES

Quant Method C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title 209 625/TCLP calibration table Last Update Tue Jan 22 11:56:23 2002 Response via Initial Calibration DataAcq Meth GCMS0103

Internal Standards R.T. Qlon Response Cone Units Dev (Min)

1) 1,4-Dichlorobenzene-d4 11.50 152 756773 20.00 ug/1 -0.20 10) Naphthalene-d8 15.10 136 2964541 20.00 ug/1 -0.21 17) Acenaphthene-diO 20.36 164 1492964 20.00 ug/1 -0.22 29) Phenanthrene-diO 24.77 188 2044573 20.00 ug/1 -0.22 38) Chrysene-dl2 32.80 240 1194682 20.00 ug/1 -0.23 44) Perylene-dl2 36.86 264 709936 20.00 ug/1 -0.26

System Monitoring Compounds 37) 2,4-DDD 29.85 235 125031 5.56 ug/mL -0.22 Spiked Amount 5.000 Recovery = 111)20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.29 74 77178 2.32 ug/1 87 3) bis(2-Chloroethyl)ether 10.94 93 187916 3.60 ug/1 99 4) 1,3-Dichlorobenzene 11.41 146 107283 1.95 ug/1 99 5) 1,4-Dichlorobenzene 11.54 146 118458m 2.13 ug/1 6) 1,2-Dichlorobenzene 12.06 146 119768 2.33 ug/1 96 7) 2,2' - oxybi s (1 -Chloropropan 12.41 45 318262 4.78 ug/1 # 94 8) N-Nitroso-di-n-propylamine 12.78 70 140807 4.73 ug/1 96 9) Hexachloroethane 12.88 117 33778 1.67 ug/1 98 11) Nitrobenzene 13.18 77 178776 3.87 ug/1 95 12) Isophorone 13.82 82 398284 4.47 ug/1 100 13) bis(2-Chloroethoxy)methane 14.52 93 229886 3.84 ug/1 100 14) 1,2,4-Trichlorobenzene 14.99 180 96670 2.25 ug/1 98 15) Naphthalene 15.15 128 436199 3.08 ug/1 100 16) Hexachlorobutadiene 15.70 225 31077 1.48 ug/1 97 18) Hexachlorocyclopentadiene 17.88 237 449 N.D. i 19) 2-Chloronaphthalene 18.63 162 231903 2.72 ug/1 98 20) Dimethylphthalate ' 19.75 163 362523 3.65 ug/1 99 21) 2,6-Dinitrotoluene 19.96 165 60755 2.59 ug/1 97 22) Acenaphthylene 19.89 152 382977 3.20 ug/1 100 2 3) Acenaphthene 20.45 153 278640 3.26 ug/1 99 24) 2,4-Dinitrotoluene 21.12 165 72561 2.43 ug/1 91 25) Diethylphthalate 21.87 149 375901 4.09 ug/1 98 26) 4-Chlorophenyl-phenylether 22.00 2 04 127025 3.17 ug/1 98 27) Fluorene 21.96 166 292943 3.34 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 22.47 77 357029 3.76 ug/L 96

(#) = qualifier out of range (m) = manual integration REFA.D GCMS1126.M Mon Feb 04 12:50:29 2002 Page 1

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