GCMS calibration results for nitrosamines and solvents, February 2002

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Quantitation Report (QT Reviewed)

• Data File : C:\HPCHEM\1\DATA\JAN1502\CAL10.D Vial: 2 Acq On : 15 Jan 2002 9:19 am Operator: 209 GALOS Sample Inst : GC/MS 209 Misc Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 4 12:42 2002 Quant Results File: GCMS1126.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue Jan 22 11:56:23 2002 Response via : Initial Calibration DataAcq Meth : GCMS0103

Internal Standards R.T. Qlon Response Conc Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.51 152 788874 20.00 ug/l -0.19 10) Naphthalene-d8 15.10 136 3059834 20.00 ug/l -0.21 17) Acenaphthene-d10 20.36 164 1537098, 20.00 ug/l -0.22 29) Phenanthrene-d10 24.77 188 2110629 20.00 ug/l -0.22 38) Chrysene-d12 32.81 240 1118804 20.00 ug/l -0.23 44) Perylene-d12 36.86 264 6.68791 20.00 ug/l -0.26

System Monitoring Compounds 37) 2,4-DDD 0.00 235 Od 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

`~ ~r n-iv Qvalue Target Compounds 2) N-nitroso-dimethyl amine 5.27 74 375062 10.81 ug/l 95 3) bis(2-Chloroethyl)ether 10.95 93 630014 11.57 ug/l 99 4) 1,3-Dichlorobenzene 11.40 146 566433 9.87 ug/l 99 5) 1,4-Dichlorobenzene 11.54 146 577934 9.96 ug/l 99 6) 1,2-Dichlorobenzene 12.05 146 542689 10.14 ug/l 99 7) 2,2'-oxybis(1-Chloropropan 12.40 45 962144 3.8 ug/l 100 8) N-Nitroso-di-n-propylamine 12.78 70 403737 ug/l 97 9) Hexachloroethane 12.88 117 237293 11.2. 5 ug/l 98 11) Nitrobenzene 13.18 77 610031 12. ug/l 98 12) Isophorone 13.82 82 1096657- 11.94 ug/l 99 13) bis(2-Chloroethoxy)methane 14.52 93 702121 11.37 ug/l 100 14) 1,2,4-Trichlorobenzene 14.99 180 439440 9.89 ug/l 98 15) Naphthalene 15.15 128 1512464 10.34 ug/l 99 16) Hexachlorobutadiene 15.70 225 229841 10.62 ug/l 98 18) Hexachlorocyclopentadiene 17.88 237 56357 5.09 ug/l 97 19) 2-Chloronaphthalene 18.63 162 835269 9.53 ug/l 99 20) Dimethylphthalate 19.75 163 984255 9.64 ug/l 100 21) 2,6-Dinitrotoluene 19.96 165 219614 9.10 ug/l 99 22) Acenaphthylene 19.89 152 1252155 10.16 ugh1 99 23) Acenaphthene 20.45 153 874074 9.92 ug/l 100 24) 2,4-Dinitrotoluene 21.12 165 272577 8.88 ug/l 96 25) Diethylphthalate 21.88 149 996908 10.55 ug/l 99 26) 4-Chlorophenyl-phenylether 22.00 204 410480 9.95 ug/l 97 27) Fluorene 21.96 166 893932 9.89 ug/l 99 28) Azobenzen/ 1,2-Diphenylhyd 22.47 77 1117503 11.44 ug/L 96 ------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration CAL10.D GCMS1126.M Mon Feb 04 12:43:49 2002 Page 1

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