GCMS analysis results, sample AE12288, June 2002

NYC 9/11 Public Portal Document Llbrary bearen compound Keporc Data File : C:\MSDCHEM\l\DATA\052902\12288.D Vial: 7 Acq On : 29 May 2002 2:58 pm Operator: McLean Sample : gc/ms scan 5/24 fb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integfator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 Acetic acid, chloro-, ethyl... Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T.

3.74 1.25 ug/L 893623 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 2 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9 2 3 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 4 Borane, trifluoro- 68 BF3 007637-07-2 1 Abundance Scan 113 (3.743 min): 12288.D (-110) (-) m/z 49.10 100.00 40

50001

41 86 ‘ ■ i ■ ■ • • i • ' ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ' 3.40 3.60 3.80 4.00

miz-> 0- A 10 20 30 40 50 58 60 70 90 100 80 I 110 120 130 m/z 86.00 19.56% Abundance #108005: Acetic acid, chloro-, ethyl ester 23

5000 3.40 3.60 3.80 4.00 | 77 42 49 m/z 41.10 14.61%| 14

niz-> 0- . 10pallijon ++35— 144— 60 70 80| 889094 100 107110 120122 130 20 30 40 50 59 65 ' ’'I ' 111 111 I ■ 1 " i ■ ‘'' ' I ■1 |,ri ।। i ।1 ■ 111 11

Abundance #1082: Ethanol, 2,2-dichloro- 31

3.40 3.60 3.80 4.00

M 5000 m/z 51.10 12.66%

25 , 37 43 49 55 61 70 77,83 96 103 114 0- ■ ' I " 1111 ‘ '‘''l 11 * I'1। ■ > > 111 ' । —IPI iz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate ‘ ' I ' ‘ ' 1 I ‘ ‘ ' I ‘ ‘ ' I ‘ ‘ ‘ ‘ I 1 31 3.40 3.60 3.80 4.00 m/z 47.10 / 12.42% 59 5000 45 74

iz—> 0 +1625 +3944———— t 10 20 30 40 50 60 70 80 90 100 110 120 130 66 , 81 93 !■' 1 1 1 ' ‘ I 1 ‘ ‘ ‘ I ' ‘ ‘ ' I ‘ ‘ ' 1 ‘ ‘ 127 ■ I ' ' I ' ' ' ■ i ■ ■ ■ ■ i • ■ ■ ■ i ■ • ■ ■ i ■ ■ ■ 1 i ■ 3.40 3,60 3.80 4.00

12288.D 052202.M Mon Jun 03 09:37:03 2002 Page 5

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