GCMS calibration data for sample AE11931, May 2002

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Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052302\11931.D Vial: 11 Acq On : 23 May 2002 6:07 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 1 lH-Pyrazole, 1-methyl- Concentration Rank 19

R.T. EstConc Area Relative to ISTD R.T.

3.54 0.28 ug/L 166466 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1H-Pyrazole, 1-methyl- 82 C4H6N2 000930-36-9/7 2 lH-Pyrazole, 3-methyl- 82 C4H6N2 001453-58-3 7 3 lH-Pyrazole, 3-methyl- 82 C4H6N2 001453-58/3 7 4 1H-Imidazole, 1-methyl- 82 C4H6N2 000616-47-7 7 Abundance Scan 78 (3.538 min): 11931.D (-71) (-) m/z 74.00 00.00% 74

82 5000 ' ■ I ■ W' I , f. ■. I, 39 47 35 39 43 3.20 3.40 3.60 3.80 . ........... ......... ......... .. in [ill If Illi । Jr 35. . m/ z 82.00 52.55% O hPpr

A ■’T1' miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #116319:1 H-Pyrazole, 1-methyl- 82

5000 -3.20“ 3.40 3.60 3.80 54 m/z 76.00 34.00% 28 42 , 39 | 51| 01 ‘ L i ■" ■ i।., ।. 111 11.... ।. 1111111, ।.... 1111 11... ।. i i" ■ ■ i “ ‘ ■ i “ " I — n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #116318:1 H-Pyrazole, 3-methyl- 82 ■ ।111 ■ । 3.20 3.40 3.60 3.80 5000 m/z 84.00 25.13% 54 28

miz-> 01 ....... ... +3+ TDWTITNT TT HTTP 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 6467 77

Abundance #32527:1 H-Pyrazole, 3-methyl- 82 3.20 3.40 3.60 3.80

a/h m/z 47.10 18.80% 5000 54 27 42 miz—> 0 ---33547457 6467 7679 85.— 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 11 ■ 111 “ 111 ‘‘11' " I ' i ■ ■ • ■ i ■ ■ ■ ■ i ■ ‘ 3.20 3.40 3.60 ■ i ■ • • ■ i 3.80

11931.D 052202.M Wed May 29 09:50:55 2002 Page 4

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