GCMS analysis report sample AE09677, May 23, 2002

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Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052102\9677.D Vial: 15 Acq On : 22 May 2002 12:44 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 Phosphonic difluoride Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. 3.99 0.75 ug/L 523093 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phosphonic difluoride 86 F2HOP 014939-34-5 5 2 2-Butenoic acid, (E)- 86 C4H602 000107-93-7 4 3 4H-l,2,4-Triazol-4-amine 84 C2H4N4 000584-13-4/4 4 Acetaldehyde, dimethylhydrazone 86 C4H10N2 007422-90-4 4 Abundance Scan 155 (3,990 min): 9677. D (-154) (-) m/z 86.00 100.00% AMw. i '

5000 85

MMaat. 43 35 4750 40 1 i ■ 1 • ■ i T 1 I ' ' 3.60 3.80 4.00 4.20 4.40 0 ■ i ■ “ ■ ‘"i■ i ■ “*i■ “■ r “ ‘i “ “i ■ ■ ■ • ' i ■" ‘ i “ • m/ z 84.00 92.74% m/z-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34889: Phosphonic difluoride 86

5000 69 3.60 3.80 4.00 4.20 4.40 66 m/z 43.10 35.84% 47

n/z-> 0 TI 11111111731 31 TP ’1***1* 50 “ ■ ■ i ■ “ 11 ‘ ■ ■ ■ r 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 i ■ ■ • ■ i ■ • ■ ■i ■ ‘ ■ ■ nym-rp-r MMYYMMpHMArvop—k, Abundance #34651:2-Butenoic acid, (E)- 85 41 1II*III’IIIII*-41I’ 3.60 3.80 4.00 4.20 4.40 5000 m/z 35.10 28.57% 69

Ol TI 27 3& 45

241131341 +45053,5760.66/,72. 7982 , 89— 1111 *11! W hht NAWdad miz-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #107976:4H-1,2,4-Triazol-4-amine 23 3.60 3.80 4.00 4.20 4.40 84 m/z 50.05 25.42? 5000

18 42 _ 69 0 ...I. ?9 31..3939145. *I’53 H—57 | unn“nuumnaT I1.. . .1". iz-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

9677.D 052202.M Wed May 22 11:34:14 2002 Page 9

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