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GCMS analysis report sample AE11908, June 4, 2002

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GCMS laboratory report for sample AE11908 detecting unknown compounds and 2,4-DDD on June 4, 2002.

NYC-WTC_000013014–000013042

Folder label: “GCMS X 5-21-02 A 5-22-02

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NYC 9/11 Public Portal Document Library Search Compound Report . Data File : C: \MSDCHEM\ 1 \DATA\ 05220211908.D Vial: 15 Acq On : 23 May 2002 1:14 am Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise : Multiply: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ** Library : C:\DATABASE\NIST98.L Peak Number 5 Oxazolidine, 3-methyl- Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 3.81 0.70 ug/L 433518 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qua 1 Oxazolidine, 3-methyl- 87 C4H9NO 027970-32-7 9 2 Acetaldehyde, dimethylhydrazone 86 C4H10N2 007422-90-4/9 3 1,3-Dioxol-2-one 86 C3H203 000872-36-6 9 4 1-Pyrrolidineethanamine 114 C6H14N2 007154-73-6 9 Abundance Scan 124 (3.808 min): 11908.D (-122) (-) m/z 84.00 0.00% 84

49 42 5000 37 36 3.40 3.60 3,80 4.00 4.20

mfz~> 01 15 R — 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 "I " ‘' I''' m/z 86.00 71.95.% Abundance #3592: Oxazolidine, 3-methyl- 42 86 57 5000 30 3.40 3.60 3.80 4.00 4.20 15 m/z 49.10 57.43% 27 54 01TTTpH nllini/l If.. —H mmmpmpa HIPgor nfe-> !5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34711: Acetaldehyde, dimethylhydrazone 44 85

3.40 3.60 3.80 4.00 4.20 5000 m/z 42.00 51.59% 30 71 27 41

n/z-> 01 !5 + l m 56

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 83 — Abundance #116747:1,3-Dioxol-2-one 2? 85 3.40 3.60 3.80 4.00 4.20 42 m/z 47.05 .. 42.40% 5000 58

n/z-> 0 m 5 03 2632 3639 I" " I 46.5055.6 63Tp-rTTp-rrTp-rTTp-rrrj- 67 71 77 83 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 89-7 3.40 3.60 3.80 4.00 4.20

11908.D 052202.M Tue May 28 12:15:32 2002 Page 8

NYC-WTC_000013026

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NYC-WTC_000013026Source: NYC Law Department, mirrored locally

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