GCMS analysis report for sample AE01547, March 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02FEB21\01547.D Vial: 3 *Acq On : 21 Feb 2002 4 :52 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 3-Bromo-l-methylpyrazole Concentration Rank 13

R.T. EstConc Area Relative to ISTD R.T.

18.74 0.02 ug/L 13604 Acenaphthene -dl0 18.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Bromo-1-methylpyrazole 160 C4H5BrN2 000000-00-0 5 2 Imidazole, 4-bromo-5-methyl- 160 C4H5BrN2 000000-00-0 5 3 NAPHTHALENE-1,2,3,6,7,8-D6, 4,5-... 162 C12H6D6 104489-28-3 5 4 1,3-Benzodioxole, 5-(2-propenyl)... 162 C10H10O2 000094-59-7 5 Abundance Scan 1361 (18.738 min): 01547.D (-) m/z 162.05 100.00% 1(2

5000 /....... ......... 49 18.40 18.60 18.80 19.00 ' ' ' 01 ITTeTmpu ‘ ‘1‘4/44441********1* ■ ■ i • ■ m/z 160.10 86.24% ■n/z-> 40 50 60 70 80 90 1(X) 110 120 130 140 150 160 170 Abundance #59104:3-Bromo1-methylpyrazole 162

5000 /I........................................ 54 81 18.40 18.60 18.80 19.00 m/z 164.10 17.16% Of ■ * i ■1'1 r1 I ■ ‘i■■■■i■■ ■ ■ I' ‘I8 i • •i ‘ i • • * * i * * ’ • i ‘1 •111 • ’ • i —p niz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #59105: Imidazole, 4-bromo-5-methyl- 81 160 ■ ' i ■ ■ • ‘ i ■ ■ ■ ■ i ■ ■ ■ ■ i1 1 1 ■ । 18.40 18.60 18.80 19.00 54 m/z 48.95 11.55% 5000 42 123 ................... ................... . ...................................... 0 ‘ 11 T-T-rr • • i • *4 * i ‘ j * i • ‘ ‘ * i * ’ * • i • • ‘-1/447/1/68.4 • ।»»* ‘14*4*1** 1... I AMw/N MA / ‘1 ‘ I ‘ ' /z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #56417: NAPHTHALENE-1,2,3,6,7,8-D6,4,5-DlMETHYL- ■i■ ■■■i ■ ' ■ ’l -r-r-p-r 1(2 18.40 18.60 18.80 19.00

5000- 146

iz—> 0 ■ ■ i' ■1 ■ i ■ ‘ 40 50 ■ i • ■' ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ 60 70 80 90 119 132 - 100 110 120 130 140 150 160 170 UH

01547.D HP022102.M Mon Feb 25 10:55:25 2002 Page 11

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