GCMS analysis results for sample AE01142, Feb 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02FEB25\01142.D Vial: 8 Acq On : 25 Feb 2002 5:01 pm Operator: ‘ ’ Sample : 508 scan Inst : Instrumen Mise : February 25, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L Peak Number 7 3-Butenoic acid $$ .beta.-B... Concentration Rank 11

R.T. EstConc Area Relative to ISTD R.T. 9.90 0.07 ug/L 28692 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Butenoic acid $$ .beta.-Buteno... 86 C4H602 000625-38-7 7 2 3-Butenoic acid (CAS) $$ Vinylac... 86 C4H602 000625-38-7 7 3 1-Propanamine 59 C3H9N 000107-10-8 5 4 2-METHYL-3,3-D2-AZIRIDINE 59 C3H5D2N 030691-55-5 4 Abundance Scan 578 (9.899 min): 01142.D (-) m/z 59.00 100.00% 59

5000

41 45 86 AN 9.60 9.80 AAA 10.00 10.20

n/z-> Of —.I,.... ■' i ■'' ‘ i ■ ■ ‘11' ■1 ■ i' 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ■ i ■ ■' i ■ ■' ■ i ■11 ■ i11' ■ i' ■ ■11111111 ■ ‘11'11 ■ i ■ m/z 45.00 16.73% Abundance #3753:3-Butenoic acid $$ .beta.-Butenoic acid $$ Acetic a... 39 A 5000 12 45 9.60 9.80 10.00 10.20 58 86 m/z 86.00 14.86% 68 01 ' H "1111111111 11 ■11 ppg — ' i ’11 ■ i ■ n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3751: 3-Butenoic acid (CAS) $$ Vinylacetic acid $$ .beta.... 39 9.60 9.80 10.00 10.20 5000 42 m/ z 58.10 14.45% 45 58 86 68 0! ■ i' ■ ■ ■ i' ' ■ i'1 '' i ' ■' r '1' i ■ 11’1 ■ ■ i ■' " I 1 ■ ‘ i " ■ ‘ i ■ m/z- > 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #653:1-Propanamine 33 9.60 9.80 10.00 10.20 m/z 41.10 11.83% 5000

59 27

n/z-> 0 TIII 20 —H 37 42 56, TTH 1 ' I 111' |11' 1111' 111 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 " i ■ ■ ‘' i ■ ■ ■ ■ ir ■' ■ r ■'' i1 ■ ■ ■ i ■ ■ ■ ■ i1 9.60 9.80 10.00 10.20

01142.D HP022102.M Tue Feb 26 08:30:35 2002 Page 9

NYC-WTC_000003535