NYC 9/11 Public Portal Document
Respirable Silica:
Organic
Componngs:
Dioxins:
OT'd = $6:2% -Z00z ET wey
NYC-WTC_000144655
The overwhelming majority of 861 silica samples (excluding bulk end blank -
_ samples) show no detectable levels of airborne silica. Huwever, 54 expocures’
exceeded the PEL. The highest sample result was appreximately twenty-one
times the OSHA limit (jack hammening concrete 16 feet below grade), The
other elevated exposures were approximately one to fourteen times the OSHA
Iimtt, These exposures oconrred during: 1) pre-drilling /slurry walt 2) jack
hammering, 3) rubble removal and loading operations near the Winter Garden;
4) during the breaking up of concrete in the pit; 5) while drilling the concrete
slurry wall, 6) flagging operations in pit, and 7) while chipping concrete with
power tools during demolition activities at 7 WTC’'s parking yamge. Most of
the work areas where apparent overexposures to silica occusred were in the
. rubble pile/pit; an srea where OSHA continues to enconrage the use of
respiratory protection.
OSHA has taken a total of 652 samples (excluding bulk and blank samples)
for organic compounds such as acetaldehyde, acrolein, acrylositrile, benzene,
2-butanone, carbofurans, dioxin, PCBs, ethyl benzene, formaldehyde, Freon
R-22 (chlorodifiouromethane), hexone, isocyanates (e.g. MDI, TDD,
perchloroethyiene, polynuclear aromatics, phosgene, styrene, toluene, 1.3
butadiene, trichloroethylene, viny! chloride, ghutaraldehyde, and xylene.
Screening samples initially showed elevates levels of some organic chemicals
resulting from the fires burning in the rubble pile. Subsequent personal and
axca samples show worker exposure levels to be below OSHA limits.
However, one personal sample result for a benzene sample ken was found to
be at the 8-br. OSHA Allowable Limit concentration of 1 pn. This was found -
on a backhoe operator moving debris on 10/7/01. See information beluw for
the specific counts in regards to polynuclear aromatics, Proon R-22, phosgene
and dioxin. .
OSHA has taken 10 dioxin samples (excluding blanks) in the plume over bot
spote in (and around the perimeter of) the rubble pile. Dioxix levels detected
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