GCMS calibration data sheet, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\APR0102\CAL2 5A.D •Vial: 32 Acq On 2 Apr 2002 12:03 pm Operator: Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 2 12:52 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.26 152 652678 20.00 ug/1 -0.09 10) Naphthalene-d8 15.89 136 2413917 20.00 ug/1 -0.10 17) Acenaphthene-dlO 21.20 164 1371875 20.00 ug/1 -0.11 29) Phenanthrene-dlO 25.64 188 2035220 20.00 ug/1 -0.12 38) Chrysene-dl2 33.70 240 1159889 20.00 ug/1 -0.14 44) Perylene-dl2 37.95 264 631091 20.00 ug/1 -0.18

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.90 74 388927 17.57 ug/1 # 70 3) bis(2-Chloroethyl)ether 11.66 93 628732 17.63 ug/1 89 4) 1,3-Dichlorobenzene 12.16 146 674182 18.30 ug/1 98 5) 1,4-Dichlorobenzene 12.30 146 681047 18.44 ug/1 99 6) 1,2-Dichlorobenzene 12.82 146 629197 18.27 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.13 45 838833 16.72 ug/1 98 8) N-Nitroso-di-n-propylamine 13.53 70 395146 17.03 ug/1 # 86 9) Hexachloroethane 13.66 117 243813 17.66 ug/1 92 11) Nitrobenzene 13.94 77 591279 17.92 ug/1 92 12) Isophorone 14.59 82 1121221 17.92 ug/1 98 13) bis(2-Chloroethoxy)methane 15.26 93 738860 18.04 ug/1 98 14) 1,2,4-Trichlorobenzene 15.77 180 558133 19.70 ug/1 98 15) Naphthalene 15.95 128 1701795 19.07 ug/1 99 16) Hexachlorobutadiene 16.49 225 283068 20.04 ug/1 100 18) Hexachlorocyclopentadiene 18.68 237 187741 20.21 ug/1 98 19) 2-Chloronaphthalene 19.46 162 1055650 .17.92 ug/1 96 20) Dimethylphthalate 20.55 163 1216132 17.62 ug/1 99 21) 2,6-Dinitrotoluene 20.76 165 285716 17.05 ug/1 # 80 22) Acenaphthylene 20.72 152 1480845 17.59 ug/1 99. 23) Acenaphthene 21.29 153 1040941 17.69 ug/1 98 24) 2,4-Dinitrotoluene 21.93 165 365093 16.28 ug/1 # 78 25) Diethylphthalate 22.68 149 1142027 17.04 ug/1 96 26) 4-Chlorophenyl-phenylether 22.83 204 542045 18.89 ug/1 92 27) Fluorene 22.81 166 1139352 18.30 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.30 77 1122644 15.63 ug/L # 83

(#) = qualifier out of range (m) = manual integration CAL25A.D GCMS0403.M Fri Apr 05 10:19:19 2002 Page 1

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