GCMS reference standard results, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\MSDCHEM\l\DATA\031702\311REFl.D Vial: 3 Acq On : 17 Mar 2002 10:26 am Operator: McLean Sample : 3/11/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 21 14:56:31 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1407705 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3686118 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.13 164 2048466 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3156382 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 2864119 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1568985 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 270932 7.20 ug/L 0.00 Spiked Amount 5.000 Recovery = 144.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 139638 4.42 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 475854 9.55 ug/L 82 4) 1,3 - Dichlorobenze 9.38 146 185828 3.77 ug/L 99 5) 1,4 - Dichlorobenzene 9.59 146 219322 4.46 ug/L 98 6) 1,2 - Dichlorobenzene 9.96 146 235008 5.17 ug/L 99 7) 2,2 ' - oxybis (1-Chloropr 10.43 45 1147688 10.11 ug/L 98 8) N-Nitroso-di-n-propylamine 10.75 70 419287 11.70 ug/L 99 9) Hexachloroethane 10.86 117 41391 2.24 ug/L 96 11) Nitrobenzene 11.10 77 517028 7.79 ug/L 95 12) Isophorone 11.81 82 1197886 9.81 ug/L 98 13) bis(2-Chloroethoxy) methan 12.55 93 623510 8.48 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 208725 4.95 ug/L 99 15) Naphthalene 13.08 12 8 1227552 8.01 ug/L 99 16) Hexachlorobutadiene 13.53 225 32662 1.38 ug/L 99 18) Hexachlorocyclopentadiene 15.60 237 7683 0.43 ug/L 96 19) 2-chloronaphthalene 16.51 162 725976 ■7,76 ug/L 98 20) Dimethylphthalate 17.59 163 1199517 10.75 ug/L 99 21) 2,6-Dinitrotoluene 17.70 165 214913 9.05 ug/L 96 22) Acenaphthylene 17.70 152 1268546 9.78 ug/L 99 23) Acenaphthene 18.22 153 821733 9.32 ug/L 97 24) 2,4-Dinitrotoluene 18.85 165 296206 8.71 ug/L 100 25) Diethylphthalate 19.72 149 1161856 12.09 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.89 204 480623 9.39 ug/L 97 27) Fluorene 19.76 166 1081788 10.40 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.34 77 1343450 9.48 ug/L 99 30) N-Nitrosodiphenylamine 20.26 169 659866 9.73 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.32 248 285086 10.23 ug/L 89 32) Hexachlorobenzene 21.34 284 261504 8.90 ug/L 99 33) Phenanthrene 22.56 178 1590697 10.88 ug/L 99 34) Anthracene 22.70 178 1465254 10.10 ug/L 100 35) Di-n-butylphthalate 24.65 149 2078349 12.41 ug/L 99 36) Fluoranthene 26.06 202 1875752 11.29 ug/L 97 3 9) Pyrene 26.69 202 1965285 9.93 ug/L 97 40) Butylbenzylphthalate 29.05 149 848112 10.00 ug/L 99 41) Benzo (a) antracene 30.29 228 1554392 10.34 ug/L 98 42) Bis (2-ethylhexyl) phthala 30.91 149 1175471 10.49 ug/L 98 43) Chrysene 30.38 228 1654585 11.58 ug/L 99 45) Di-n-Octylphthalate 32.75 149 1681965 9.98 ug/L 97 46) Benzo (b) fluoranthene 33.23 252 1254084 11.34 ug/L 100

(#) = qualifier out of range (m) = manual integration 311REF1.D 5080302.M Thu Mar 21 14:56:56 2002 Page 1

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