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GCMS blank analysis results, March 2002

Machine-extracted title · confidence 90%

Laboratory report showing blank sample analysis for volatile organic compounds using GCMS on March 25, 2002.

NYC-WTC_000059338–000059345

Folder label: “GCMS X 3/11/02 A 3/17/02

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NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\032502\311LBR.D Vial: 4 Acq On : 25 Mar 2002 9:21 am Operator: McLean Sample : L BLK 3/11 RE-INJ Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 25 11:11:00 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For.Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCANB

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.55 150 1049489 20.00 ug/L 0.00 10) Naphthalene-d8 13.02 136 3346780 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.13 164 1865444 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.49 188 2712123 20.00 ug/L 0.00 38) Chrysene-dl2 30.30 240 2065122 20.00 ug/L -0.02 44) Perylene-dl2 34.18 264 1029126 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 217671 6.73 ug/L 0.00 Spiked Amount 5.000 Recovery. = 134.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-chloroethyl) ether 0.00 93 0 N.D. 4) 1,3 - Dichlorobenze 0.00 146 0 N.D. 5) 1,4 - Dichlorobenzene 0.00 146 0 N.D. 6) 1,2 - Dichlorobenzene 0.00 146 0 N.D. 7) 2,2 ' - oxybis (1-Chloropr 0.00 45 0 N.D. 8) ■ N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy) methan 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 0.00 128 0 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. d 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 0.00 149 0 N.D. 26) 4-Chlorophenyl-phenyl ethe 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 30) N-Nitrosodiphenylamine 0.00 169 0 N.D. 31) 4-Bromophenyl-phenyl ether 0.00 248 0 N.D. 32) Hexachlorobenzene 0.00 284 0 N.D. 33) Phenanthrene 0.00 178 0 N.D. 34) Anthracene 0.00 178 0 N.D. 35) Di-n-butylphthalate 24.65 149 21258 0.15 ug/L 88 36) Fluoranthene 0.00 202 0 N.D. 3 9) Pyrene 0.00 202 0 N.D. 40) Butylbenzylphthalate 0.00 149 0 N.D. 41) Benzo (a) antracene 0.00 228 0 N.D. d 42) Bis (2-ethylhexyl) phthala 30.92 149 13715 0.17 ug/L 76 43) Chrysene 0.00 228 0 N.D. d 45) Di-n-Octylphthalate 0.00 149 0 N.D. 46) Benzo (b) fluoranthene 0.00 252 0 N.D.

(#) = qualifier out of range (m) = manual integration 311LBR.D 5080302.M Mon Mar 25 11:11:31 2002 Page 1

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