GCMS calibration results for volatile organics, February 2002

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• Data File : C:\HPCHEM\l\DATA\FEB1102\REFA.D Vial: 17 Acq On : 12 Feb 2002 1:47 am Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 199:462002 <Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 13 11:43:23 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.35 152 274026 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1037172 20.00 ug/1 0.00 17) Acenaphthene-dlO 21.31 164 551700 20.00 ug/1 0.00 29) Phenanthrene-dlO 25.75 188 797875 20.00 ug/1 -0.01 38) Chrysene-dl2 33.82 240 553582 20.00 ug/1 -0.02 44) Perylene-dl2 38.11 264 350204 20.00 ug/1 -0.01

System Monitoring Compounds 37) 2,4-DDD 30.84 235 44408 5.54 ug/mL 0.34 Spiked Amount 5.000 Recovery = 110.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.98 74 21238 1.94 ug/1 98 3) bis(2-Chloroethyl)ether 11.73 93 54568 3.03 ug/1 99 4) 1,3-Dichlorobenzene 12.25 146 42556 1.99 ug/1 99 5) 1,4-Dichlorobenzene 12.39 146 45869m 2.10 ug/1 6) 1,2-Dichlorobenzene 12.91 146 44864 2.16 ug/1 97 7) 2,2'-oxybis(1-Chloropropan 13.23 45 89505 3.28 ug/1 97 8) N-Nitroso-di-n-propylamine 13.62 70 37706 2.93 ug/1 98 9) Hexachloroethane 13.76 117 12821 .1.47 ug/1 97 11) Nitrobenzene 14.03 77 52258 2.45 ug/1 99 12) Isophorone 14.68 82 107070 2.97 ug/1 100 13) bis (2-Chloroethoxy)methane 15.36 93 65243 2.91 ug/1 99 14) 1,2,4-Trichlorobenzene 15.87 180 38546 2.17 ug/1 97 15) Naphthalene 16.05 128 150903 2.73 ug/1 100 16) Hexachlorobutadiene 16.59 225 14063 1.32 ug/1 94 18) Hexachlorocyclopentadiene 18.79 237 2007 0.25 ug/1 # 77 19) 2-Chloronaphthalene 19.56 162 87269 2.65 ug/1 98 20) Dimethylphthalate 20.64 163 120378 3.14 ug/1 100 21) 2,6-Dinitrotoluene 20.86 165 16056 1.85 ug/1 # 94 22) Acenaphthylene 20.83 152 126946 2.67 ug/1 99 23) Acenaphthene 21.40 153 98410 2.96 ug/1 99 24) 2,4-Dinitrotoluene 22.03 165 19432 1.77 ug/1 97 25) Diethylphthalate 22.78 149 120367 3.02 ug/1 98 26) 4-Chlorophenyl-phenylether 22.93 204 49578 2.89 ug/1 93 27) Fluorene 22.92 166 103526 2.86 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 115647 2.76 ug/L 99

(#) = qualifier out of range (m) = manual integration REFA.D GCMS0208.M Tue Feb 19 09:48:58 2002 Page 1

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