GCMS analysis report for sample AE01002, Mar 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\DATA\022802\0226REFA.D Vial: 3 Acq On : 28 Feb 2002 12:38 pm Operator: McLean Sample : GC MS SCAN 2/27 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 13 06:41:33 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.57 150 1203717 20.00 ug/L 0.00 10) Naphthalene-d8 13.05 136 3092397 20.00 ug/L 0.00 17) Acenaphthene-diO 18.17 164 1685957 20.00 ug/L 0.00 29) Phenanthrene-diO 22.52 188 2604968 20.00 ug/L 0.00 38) Chrysene-dl2 30.34 240 2380064 20.00 ug/L -0.02 44) Perylene-dl2 34.21 264 1640277 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.47 235 160671 3.89 ug/L 0.00 Spiked Amount 5.000 Recovery = 77.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.63 74 153454 4.22 ug/L 100 3) bis(2-chloroethyl) ether 9.01 93 400580 7.03 ug/L 80 4) 1,3 - Dichlorobenze 9.41 146 131106 2.44 ug/L 98 5) 1,4 - Dichlorobenzene 9.62 146 151605 2.84 ug/L 97 6) 1,2 - Dichlorobenzene 10.00 7) 2,2 1 - oxybis (l-Chloropr 10.45 8) N-Nitroso-di-n-propylamine 10.79 146 45 70 168059 911336 286585 3.39 ug/L 6.61 ug/L 6.56 ug/L 99 98 97 (0 9) Hexachloroethane 10.89 117 23338 1.08 ug/L 94 11) Nitrobenzene 11.13 77 395045 5.48 ug/L 95 12) Isophorone 11.84 82 844648 6.42 ug/L 100 13) bis(2-Chloroethoxy) methan 12.58 93 503667 6.32 ug/L 98 14) 1,2,4-Trichlorobenzene 12.93 180 144452 3.28 ug/L 100 15) Naphthalene 13.11 128 906359 5.57 ug/L 99 16) Hexachlorobutadiene 13.56 225 14852 0.61 ug/L 95 18) Hexachlorocyclopentadiene 15.64 237 4247m 0.26 ug/L 19) 2-chloronaphthalene 16.54 162 501741 5.21 ug/L 99 20) Dimethylphthalate 17.62 163 840498 7.31 ug/L 99 21) 2,6-Dinitrotoluene 17.72 165 143019 6.10 ug/L 96 22) Acenaphthylene 17.72 152 950058 7.17 ug/L 99 23) Acenaphthene 18.25 153 604874 6.57 ug/L 97 24) 2,4-Dinitrotoluene 18.88 165 180847 5.37 ug/L 99 25) Diethylphthalate 19.76 149 819092 8.32 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.93 204 339553 6.63 ug/L 98 27) Fluorene 19.78 166 788063 7.51 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.37 77 959775 6.38 ug/L 98 30) N-Nitrosodiphenylamine 20.29 169 510348 7.34 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.35 248 191743 6.97 ug/L 97 32) Hexachlorobenzene 21.37 284 174184 6.15 ug/L 96 33) Phenanthrene 22.59 178 1152355 7.63 ug/L 100 34) Anthracene 22.74 178 1060211 7.31 ug/L 98 35) Di-n-butylphthalate 24.68 149 1164027 6.67 ug/L 99 36) Fluoranthene 26.09 202 1214825 6.99 ug/L 99 39) Pyrene 26.71 202 1278288 6.61 ug/L 97 40) Butylbenzylphthalate 29.08 149 470746 5.68 ug/L 98 41) Benzo (a) antracene 30.31 228 947629 6.07 ug/L 100 42) Bis (2-ethylhexyl) phthala 30.95 149 663140 6.14 ug/L 98 43) Chrysene 30.40 228 1008315 6.62 ug/L 97 45) Di-n-Octylphthalate 32.79 149 877705 5.22 ug/L 99 46) Benzo (b) fluoranthene 33.26 252 867665 6.32 ug/L 99

(#) = qualifier out of range (m) = manual integration 0226REFA.D 5080202.M Wed Mar 13 06:42:09 2002 Page 1

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