GCMS reference data for sample AE00277, Jan 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN09\0107RA.D Vial: 1 Aq On : 9 Jan 2002 6:09 pm Operator: Sample : ref ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: SPLIT.P Quant Time: Jan 10 08:37:44 2002 Quant Results File: SCAN508.RES

Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Last Update : Wed Jan 09 12:49:14 2002 Response via : Initial Calibration DataAcq Meth : SCAN508

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.72 152 1310037 20.00 ug/L 0.00 10) Naphthalene-d8 13.19 136 5598367 20.00 ug/L -0.02 17) Acenaphthene-diO 18.34 164 2928078 20.00 ug/L -0.01 29) Phenanthrene-dlO 22.63 188 4891140 20.00 ug/L -0.03 38) Chrysene-dl2 30.49 240 4455939 20.00 ug/L -0.02 44) Perylene-dl2 34.42 264 3332087 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-DDD 27.73 235 379680 4.91 ug/L 0.00 Spiked Amount 5.000 Recovery = 98.20%

Target Compounds Qvalue 2) N-nitroso-dimethylamine 4.00 74 157451 2.82 ug/L 53 3) bis (2--Chloroethyl) ether 9.24 93 403181 4.48 ug/L 70 4) 1,3-Dichlorobenzene 9.61 146 208887 2.13 ug/L 98 5) 1,4-Dichlorobenzene 9.76 146 224899 2.28 ug/L 96 6) 1,2-Dichlorobenzene 10.24 146 230062 2.62 ug/L 99 7) 2,2‘oxybis (1-Chloropropa 10.68 45 553405 3.65 ug/L # 72 8) N-nitroso-di-n-propylamine 11.06 70 266779 3.86 ug/L 78 9) Hexachloroethane 11.03 117 46881 1.33 ug/L 98 11) Nitrobenzene 11.35 77 296866 2.84 ug/L 87 12) Isophorone 12.03 82 750706 3.98 ug/L 93 13) bis (2-Chloroethoxy) metha 12.77 93 501589 4.48 ug/L 91 14) 1,2,4-Trichlorobenzene 13.11 180 182520 2.50 ug/L 93 15) Naphthalene 13.25 128 973531 3.63 ug/L 98 16) Hexachlorobutadiene 13.84 225 45757 1.18 ug/L 91 18) Hexachlorocyclopentadiene 15.96 237 7445 0.28 ug/L # 85 19) 2-Chloronaphthalene 16.65 162 535926 3.31 ug/L 93 20) Dimethylphthalate 17.88 163 876199 4.53 ug/L 94 21) 2,6-Dinitrotoluene 18.06 165 97065 2.57 ug/L 84 22) Acenaphthylene 17.86 152 902245 3.83 ug/L 98 23) Acenaphthene 18.42 153 682174 4.06 ug/L 99 24) 2,4-Dinitrotoluene 19.17 165 114168 2.31 ug/L 96 25) Diethylphthalate 20.00 149 885277 4.78 ug/L 99 26) 4-Chlorophenyl-phenylether 20.03 204 349251 4.48 ug/L 80 27) Fluorene 19.91 166 822568 4.31 ugIL 97 28) Azobenzene 20.46 77 929600 4.02 ug/L 83 30) N-nitrosodiphenylamine 20.43 169 517925 4.17 ug/L 98 31) 4-Bromophenyl-phenylether 21.44 248 201399 3.96 ug/L 90 32) Hexachlorobenzene 21.77 284 211249 3.93 ug/L 98 33) Phenanthrene 22.70 178 1318197 4.89 ug/L 99 34) Anthracene 22.83 178 1232481 4.71 ug/L 98

(#) = qualifier out of range (m) = manual integration 0107RA.D SCAN508.M Thu Jan 10 08:37:45 2002 Page 1

NYC-WTC_000050823