GCMS reference standard results for volatile organics, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAYO8O2\REFA2.D Vial: 15 Acq On 9 May 2002 12:16 am Operator: Sample GC/MS SCAN 5/7 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 9 15:43 2002 Quant Results File: GCMS0507.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0507.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu May 09 14:27:53 2002 Response via : Initial Calibration DataAcq Meth : GCMS0507

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 424633 40.00 ug/1 0.00 10) Naphthalene-d8 15.82 136 1557358 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.14 164 847603 40.00 ug/1 0.00 30) Phenanthrene-diO 25.57 188 1140398 40.00 ug/1 0.00 38) Chrysene-dl2 33.64 240 597788 40.00 ug/1 0.00 44) Perylene-dl2 37.86 264 338400 40.00 ug/1 0.00

System Monitoring Compounds 2 8) TCMX 23.27 209 38995 9.25 ug/L 0.00 Spiked Amount 10.000 Recovery = 92.50%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.83 74 124140 11.61 ug/1 99 3) bis(2-Chloroethyl)ether 11.59 93 238428 17.19 ug/1 95 4) 1,3-Dichlorobenzene 12.09 146 168895 12.84 ug/1 97 5) 1,4-Dichlorobenzene 12.24 146 181937 12.64 ug/1 99 6) 1,2-Dichlorobenzene 12.75 146 184256 14.70 ug/1 98 7) 2,21-oxybis(1-Chloropropan 13.07 45 492679 18.32 ug/1 98 8) N-Nitroso-di-n-propylamine 13.46 70 180235 18.19 ug/1 98 9) Hexachloroethane 13.60 117 43148 8.42 ug/1 98 11) Nitrobenzene 13.87 77 216838 17.15 ug/1 97 12) Isophorone 14.52 82 506868 20.45 ug/1 97 13) bis(2-Chloroethoxy)methane 15.20 93 289066 18.00 ug/1 100 14) 1,2,4-Trichlorobenzene 15.71 180 154984 14.33 ug/1 99 15) Naphthalene 15.89 128 576147 17.98 ug/1 100 16) Hexachlorobutadiene 16.43 225 39557 7.90 ug/1 99 18) Hexachlorocyclopentadiene 18.63 237 13107 3.05 ug/1 99 19) 2-Chloronaphthalene 19.39 162 352568 19.04 ug/1 98 20) Dimethylphthalate 20.48 163 435414 18.67 ug/1 100 21) 2,6-Dinitrotoluene 20.70 165 83373 16.72 ug/1 95 22) Acenaphthylene 20.66 152 551783 16.72 ug/1 99 23) Acenaphthene 21.22 153 367882 18.70 ug/1 100 24) 2,4-Dinitrotoluene 21.86 165 94625 17.60 ug/1 96 25) Diethylphthalate 22.61 149 419451 20.09 ug/1 99 26) 4-Chlorophenyl-phenylether 22.77 204 181338 17.57 ug/1 99 27) Fluorene 22.74 166 396982 19.14 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 441527 17.08 ug/L 97 31) N-Nitrosodiphenylamine 23.15 168 141359 19.84 ug/1 98 32) 4-Bromophenyl-phenylether 24.23 248 99076 17.57 ug/1 98 33) Hexachlorobenzene 24.67 284 119810 18.59 ug/1 98 34) Phenanthrene 25.64 178 523958 19.15 ug/1 100

(#) = qualifier out of range (m) = manual integration REFA2.D GCMS0507.M Thu May 09 15:45:23 2002 Page 1

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