GCMS reference data for sample AE06760, April 16-19, 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\l\DATA\041602\C40A0416.D Vial: 2 Acq On : 16 Apr 2002 9:12 am Operator: Bohik * Sample : C40 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 16 09:59:38 2002 Quant Results File: 5080402BBC.RES

Quant Method : C:\MSDCHEM\l\5973N\5080402BBC.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Apr 15 15:58:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.41 152 506591 40.00 ug/L 0.00 10) Naphthalene-d8 12.89 136 2086657 40.00 ug/L 0.00 17) Acenaphthene-diO 17.99 164 1163184 40.00 ug/L 0.00 30) Phenanthrene-dlO 22.35 188 1672333 40.00 ug/L 0.00 39) Chrysene-dl2 30.17 240 1304001 40.00 ug/L 0.01 45) Perylene-dl2 34.02 264 812221 40.00 ug/L 0.00

System Monitoring Compounds 28) TCMX (SURR) 19.96 244 45998 9.91 ug/L 0.00 Spiked Amount 10.000 Recovery = 99.10% 38) 2,4-DDD (SURR) 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery = 0.00%

Target Compounds (vu Qvalue 2) N-nitroso-dimethyl amine 3.44 74 1221060 83.35 ug/L 87 3) bls(2-chloroethyl) ether 8.85 93 1866504 86.90 ug/L 81 4) 1,3 - Dichlorobenze 9.24 146 1497915 85.35 ug/L 99 5) 1,4 - Dichlorobenzene 9.46 146 1604086 85.39 ug/L 98 6) 1,2 - Dichlorobenzene 9.83 146 1330430 86.64 ug/L 99 7) 2,2 ' - oxybis (1-Chloropr 10.30 45 2738502 85.46 ug/L 94 8) N-Nitroso-di-n-propylamine 10.65 70 1342987 87.71 ug/L 96 9) Hexachloroethane 10.72 117 703138 84.16 ug/L 96 11) Nitrobenzene 10.98 77 1884015 93.04 ug/L 98 12) Isophorone 11.69 82 3536393 87.79 ug/L 98 13) bis(2-Chloroethoxy) methan 12.44 93 2195440 89.34 ug/L 99 14) 1,2,4-Trichlorobenzene 12.77 180 1134590 84.04 ug/L 99 15) Naphthalene 12.95 128 4256667 83.42 ug/L 99 16) Hexachlorobutadiene 13.40 225 562104 86.39 ug/L 99 18) Hexachlorocyclopentadiene 15.47 237 508042 93.33 ug/L 99 19) 2-chloronaphthalene 16.38 162 2134388 90.71 ug/L 98 20) Dimethylphthalate 17.48 163 2877414 86.01 ug/L 99 21) 2,6-Dinitrotoluene 17.59 165 595235 91.34 ug/L 97 22) Acenaphthylene 17.56 152 3846670 89.42 ug/L 99 23) Acenaphthene 18.09 153 2249045 82.65 ug/L 99 24) 2,4-Dinitrotoluene 18.73 165 699661 89.14 ug/L 99 25) Diethylphthalate 19.60 149 2346578 84.48 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.77 204 1293224 84.21 ug/L 96 27) Fluorene 19.62 166 2629874 83.78 ug/L 100 29) Azobenzen/ 1,2-Diphenylhyd 20.21 77 4154745 86.02 ug/L 95 31) N-Nitrosodiphenylamine 20.14 169 1506055 84.47 ug/L 100 32) 4-Bromophenyl-phenyl ether 21.18 248 665772 86.04 ug/L 97 33) Hexachlorobenzene 21.21 284 602766 83.34 ug/L 93 34) Phenanthrene 22.42 178 3834146 82.73 ug/L 99 35) Anthracene 22.57 178 3932544 83.19 ug/L 100 36) Di-n-butylphthalate 24.52 149 4575694 86.34 ug/L 99 37) Fluoranthene 25.92 202 4295590 87.40 ug/L 91 4 0) Pyrene 26.55 202 4122088 83.82 ug/L 93 41) Butylbenzylphthalate 28.91 149 1994539 87.80 ug/L 90 42) Benzo (a) antracene 30.14 228 3357936 84.55 ug/L 99 43) Bis (2-ethylhexyl) phthala 30.78 149 2720756 84.33 ug/L 98 44) Chrysene 30.24 228 3248177 82.63 ug/L 100

(#) = qualifier out of range (m) = manual integration C40A0416.D 5080402BBC.M Tue Apr 16 10:00:47 2002 Page 1

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