GCMS reference data for sample AE06585, April 15, 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\041502\REFA0415.D Vial: 6 -. Acq On : 15 Apr 2002 2:08 pm Operator: Bohlk Sample : REFI 3/20/02 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 17 16:38:20 2002 Quant Results File: 5080402BBC.RES

Quant Method : C:\MSDCHEM\1\5973N\5080402BBC.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Tue Apr 16 18:27:45 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.41 152 437954 40.00 ug/L 0.00 10) Naphthalene-d8 12.89 136 1835139 40.00 ug/L 0.00 17) Acenaphthene-dlO 17.99 164 1022827 40.00 ug/L 0.00 30) Phenanthrene-diO 22.34 188 1462804 40.00 ug/L 0.00 39) Chrysene-dl2 30.15 240 1193436 40.00 ug/L 0.00 45) Perylene-dl2 34.01 264 711841 40.00 ug/L 0.00

System Monitoring Compounds 28) TCMX (SURR) 0.00 244 0 0.00 ug/L Spiked Amount 10.000 Recovery 0.00% 38) 2,4-DDD (SURR) 27.28 235 109761 10.08 ug/L 0.01 Spiked Amount 10.000 Recovery = 100.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.50 74 124917m 9.86 ug/L 3) bis(2-chloroethyl) ether 8.85 93 284236 15.31 ug/L 82 4) 1,3 - Dichlorobenze 9.25 146 206256 13.59 ug/L 93 5) 1,4 - Dichlorobenzene 9.45 146 219049 13.49 ug/L 98 6) 1,2 - Dichlorobenzene 9.83 146 190724 14.37 ug/L 95 7) 2,2 1 - oxybis (l-Chloropr 10.30 45 511039 18.45 ug/L 92 8) N-Nitroso-di-n-propylamine 10.62 70 218747 16.53 ug/L 95 9) Hexachloroethane 10.72 117 78950 10.93 ug/L 96 11) Nitrobenzene 10.96 77 236800 13.30 ug/L 96 12) Isophorone 11.68 82 603832 17.04 ug/L 97 13) bis(2-Chloroethoxy) methan 12.43 93 343906 15.91 ug/L 98 14) 1,2,4-Trichlorobenzene 12.77 180 172688 14.55 ug/L 98 15) Naphthalene 12.94 128 817210 18.21 ug/L 100 16) Hexachlorobutadiene 13.40 225 66512 11.62 ug/L 89 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-chloronaphthalene 16.36 162 369305 17.85 ug/L 98 20) Dimethylphthalate 17.46 163 555953 18.90 ug/L 99 21) 2,6-Dinitrotoluene 17.56 165 86661 15.12 ug/L 98 22) Acenaphthylene 17.54 152 577245 15.26 ug/L 98 23) Acenaphthene 18.07 153 471496 19.71 ug/L 97 24) 2,4-Dinitrotoluene 18.71 165 84466 12.24 ug/L 97 25) Diethylphthalate 19.58 14 9 547332 22.41 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.75 204 227095 16.82 ug/L 97 27) Fluorene 19.61 166 570213 20.66 ug/L 100 29) Azobenzen/ 1,2-Diphenylhyd 20.20 77 760745 17.91 ug/L 95 31) N-Nitrosodiphenylamine 20.11 169 264592 16.96 ug/L 99 32) 4-Bromophenyl-phenyl ether 21.17 248 114825 16.96 ug/L 86 33) Hexachlorobenzene 21.19 284 117880 18.63 ug/L 91 34) Phenanthrene 22.40 178 805861 19.88 ug/L 100 35) Anthracene 22.55 178 666798 16.13 ug/L 99 36) Di-n-butylphthalate 24.50 149 926800 19.99 ug/L 99 37) Fluoranthene 25.90 202 781412 18.18 ug/L 83 4 0) Pyrene 26.53 202 882919 19.62 ug/L 88 41) Butylbenzylphthalate 28.90 149 358310 17.23 ug/L 90 42) Benzo (a) antracene 30.12 228 615855 16.94 ug/L 99 43) Bis (2-ethylhexyl) phthala 30.77 14 9 531921 18.01 ug/L 97 44) Chrysene 30.21 228 699160 19.43 ug/L 98

(#) = qualifier out of range (m) = manual integration REFA0415.D 5080402BBC.M Wed Apr 17 16:39:19 2002 Page 1

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