GCMS reference analysis report for sample AE05902, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\031702\314REFl.D Vial: 17 Acq On 17 Mar 2002 11:29 pm Operator: McLean Sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 11:00:07 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1419374 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3753969 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.13 164 2068070 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3231385 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 3072550 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1805034 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 283103 7.34 ug/L 0.00 Spiked Amount 5.000 Recovery = 146.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 178735 5.61 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 512250 10.20 ug/L 82 4) 1,3 - Dichlorobenze 9.38 146 208470 4.20 ug/L 97 5) 1,4 - Dichlorobenzene 9.59 146 246958 4.98 ug/L 98 6) 1,2 - Dichlorobenzene 9.96 146 267508 5.83 ug/L 99 7) 2,2 ‘ - oxybis (l-Chloropr 10.43 45 1198621 10.47 ug/L 99 8) N-Nitroso-di-n-propylamine 10.75 70 415185 11.49 ug/L 99 9) Hexachloroethane 10.86 117 37622 2.02 ug/L 98 11) Nitrobenzene 11.10 77 531442 7.86 ug/L 94 12) Isophorone 11.81 82 1103314 8.87 ug/L 99 13) bis(2-Chloroethoxy) methan 12.55 93 627351 8.38 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 235289 5.47 ug/L 98 15) Naphthalene 13.08 128 1315968 8.43 ug/L 99 16) Hexachlorobutadiene 13.53 225 25959 1.08 ug/L 92 18) Hexachlorocyclopentadiene 15.61 237 7420 0.41 ug/L 90 19) 2-chloronaphthalene 16.51 162 733300 7.77 ug/L 98 20) Dimethylphthalate 17.59 163 1170102 10.38 ug/L 99 21) 2,6-Dinitrotoluene 17.70 165 211963 8.84 ug/L 96 22) Acenaphthylene 17.70 152 1315599 10.04 ug/L 99 2 3) Acenaphthene 18.22 153 866653 9.73 ug/L 99 24) 2,4-Dinitrotoluene 18.35 165 293982 8.56 ug/L 95 25) Diethylphthalate 19.72 149 1117534 11.52 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.89 204 505581 9.78 ug/L 99 27) Fluorene 19.76 166 1124632 10.71 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1345388 9.41 ug/L 96 30) N-Nitrosodiphenylamine 20.26 169 631912 9.10 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.32 248 291236 10.21 ug/L 92 32) Hexachlorobenzene 21.34 284 281702 9.36 ug/L 94 33) Phenanthrene 22.56 178 1610121 10.76 ug/L 99 34) Anthracene 22.70 178 1481312 9.97 ug/L 99 35) Di-n-butylphthalate 24.64 149 2000509 11.66 ug/L 99 36) Fluoranthene 26.06 202 1888058 11.10 ug/L 99 3 9) Pyrene 26.69 202 1963997 9.25 ug/L 97 40) Butylbenzylphthalate 29.05 149 842253 9.26 ug/L 99 41) Benzo (a) antracene 30.29 228 1595826 9.90 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 1150523 9.57 ug/L 96 43) Chrysene 30.38 228 1689253 11.02 ug/L 98 45) Di-n-Octylphthalate 32.75 149 1691849 8.73 ug/L 99 46) Benzo (b) fluoranthene 33.23 252 1361144 10.70 ug/L 100

(#) = qualifier out of range (m) = manual integration 314REF1.D 5080302.M Wed Mar 20 11:02:03 2002 Page 1

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