GCMS reference analysis report for sample AE05902, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File': C:\MSDCHEM\l\DATA\031702\314REF2.D Vial: 18 Acq On : 18 Mar 2002 12:18 am Operator: McLean Sample : 3/14/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 10:56:27 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1317659 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3434646 20.00 ug/L 0 . oc 17) Acenaphthene-dl 18.13 164 1926097 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 2949257 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 2697964 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1627358 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 250950 7.13 ug/L 0.0 0 Spiked Amount 5.000 Recovery = 142.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 150035 5.07 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 471650 10.11 ug/L 82 4) 1,3 - Dichlorobenze 9.38 146 205883 4.46 ug/L 95 5) 1,4 - Dichlorobenzene 9.59 146 243386 5.29 ug/L 93 6) 1,2 - Dichlorobenzene 9.97 146 265124 6.23 ug/L 99 7) 2,2 ’ - oxybis (l-Chloropr 10.43 45 1073955 10.11 ug/L 100 8) N-Nitroso-di-n-propylamine 10.75 70 367616 10.96 ug/L 98 9) Hexachloroethane 10.86 117 44747 2.59 ug/L 97 11) Nitrobenzene 11.10 77 465825 7.53 ug/L 95 12) 1sophorone 11.81 82 987883 8.68 ug/L 100 13) bis(2-Chloroethoxy) methan 12.55 93 579038 8.45 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 225562 5.74 ug/L 99 15) Naphthalene 13.08 128 1213640 8.50 ug/L 100 16) Hexachlorobutadiene 13.53 225 32669 1.49 ug/L 97 18) Hexachlorocyclopentadiene 15.61 237 7632 0.45 ug/L 86 19) 2-chloronaphthalene 16.51 162 690488 7.85 ug/L 97 20) Dimethylphthalate 17.59 163 1048774 9.99 ug/L 99 21) 2,6-Dinitrotoluene 17.70 165 188725 8.45 ug/L 97 2 2) Acenaphthylene 17.70 152 1185848 9.72 ug/L 99 23) Ac enaphthene 18.22 153 793009 9.56 ug/L 98 24) 2,4-Dinitrotoluene 18.85 165 256830 8.03 ug/L 99 25) Diethylphthalate 19.72 149 1022977 11.33 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.89 204 450220 9.35 ug/L 98 27) Fluorene 19.76 166 1020675 10.44 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1213818 9.11 ug/L 97 30) N-Nitrosodiphenylamine 20.26 169 581283 9.17 ug/L 100 31) 4-Bromophenyl-phenyl ether 21.32 248 273442 10.50 ug/L 99 32) Hexachlorobenzene 21.34 284 266635 9.71 ug/L 94 33) Phenanthrene 22.56 178 1476727 10.81 ug/L 98 34) Anthracene 22.70 178 1357651 10.02 ug/L 99 35) Di-n-butylphthalate 24.64 149 1826223 11.67 ug/L 99 36) Fluoranthene 26.06 202 1699010 10.95 ug/L 100 39) Pyrene 26.69 202 1778911 9.54 ug/L 99 40) Butylbenzylphthalate 29.05 149 743351 9.31 ug/L 99 41) Benzo (a) antracene 30.29 228 1392128 9.83 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 1008615 9.55 ug/L 98 43) Chrysene 30.38 228 1525206 11.34 ug/L 99 45) Di-n-Octylphthalate 32.75 149 1445544 8.27 ug/L 99 46) Benzo (b) fluoranthene 33.23 252 1179877 10.29 ug/L 99

(#) = qualifier out of range (m) = manual integration 314REF2.D 5080302.M Wed Mar 20 10:58:47 2002 Page 1

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