GCMS quantitative results for sample AE00364, March 21, 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\031902\40CAL2.D Vial: 5 Acq On 20 Mar 2002 2:23 am Operator: McLean Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 05:42:49 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.55 150 2073874 20.00 ug/L 0.00 10) Naphthalene-d8 13.04 136 4828060 20.00 ug/L 0.00 17) Acenaphthene-diO 18.14 164 2610273 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 4260332 20.00 ug/L 0.00 38) Chrysene-dl2 30.34 240 3678716 20.00 ug/L 0.02 44) Perylene-dl2 34.20 264 2341953 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 33948 0.67 ug/L 0.00 Spiked Amount 5.000 Recovery = 13.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.56 74 1802709 38.71 ug/L 100 3) bis(2-chloroethyl) ether 9.01 93 2711057 36.93 ug/L 99 4) 1,3 - Dichlorobenze . 9.39 146 2747854 37.85 ug/L 99 5) 1,4 - Dichlorobenzene 9.60 146 2734539 37.76 ug/L 99 6) 1,2 - Dichlorobenzene 9.98 146 2521291 37.61 ug/L 99 7) 2,2 ‘ - oxybis (l-Chloropr 10.44 45 6280698 37.56 ug/L 98 8) N-Nitroso-di-n-propylamine 10.80 70 2082539 39.45 ug/L 99 9) Hexachloroethane 10.87 117 1081009 39.74 ug/L 98 11) Nitrobenzene 11.14 77 3317759 38.16 ug/L 100 12) 1sophorone 11.87 82 6062142 37.88 ug/L 99 13) bis(2-Chloroethoxy) methan 12.59 93 3643865 37.84 ug/L 99 14) 1,2,4-Trichlorobenzene 12.92 180 2132527 38.58 ug/L 100 15) Naphthalene 13.10 128 7586440 37.81 ug/L 99 16) Hexachlorobutadiene 13.54 225 1227779 39.72 ug/L 100 18) Hexachlorocyclopentadiene 15.61 237 1039162 45.21 ug/L 98 19) 2-chloronaphthalene 16.53 162 4561284 38.28 ug/L 99 20) Dimethylphthalate 17.63 163 5598024 39.36 ug/L 99 21) 2,6-Dinitrotoluene 17.74 165 1186718 39.20 ug/L 97 22) Acenaphthylene 17.72 152 6327069 38.27 ug/L 99 23) Acenaphthene 18.25 153 4310298 38.35 ug/L 99 24) 2,4-Dinitrotoluene 18.89 165 1724226 39.78 ug/L 96 25) Diethylphthalate 19.77 149 4857843 39.69 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.91 204 2498989 38.31 ug/L 96 27) Fluorene 19.78 166 5032384 37.98 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.37 77 6892174 38.18 ug/L 98 30) N-Nitrosodiphenylamine 20.30 169 3461658 37.80 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.33 248 1454380 38.67 ug/L 95 32) Hexachlorobenzene 21.37 284 1490606 37.58 ug/L 98 3 3) Phenanthrene 22.59 178 7505080 38.04 ug/L 99 34) Anthracene 22.73 178 7404499 37.82 ug/L 100 35) Di-n-butylphthalate 24.66 149 8769621 38.78 ug/L 99 36) Fluoranthene 26.09 202 8763325 39.08 ug/L 99 39) Pyrene 26.72 202 9020959 35.47 ug/L 93 40) Butylbenzylphthalate 29.07 149 3983365 36.58 ug/L 98 41) Benzo (a) antracene 30.30 228 7424168 38.45 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.92 149 5169938 35.92 ug/L 99 43) Chrysene 30.41 228 6976732 38.03 ug/L 99 45) Di-n-Octylphthalate 32.77 149 8583831 34.12 ug/L 98 46) Benzo (b) fluoranthene 33.26 252 6199396 37.56 ug/L 98

(#) = qualifier out of range (m) = manual integration 40CAL2.D 5080302.M Thu Mar 21 11:50:30 2002 Page 1

NYC-WTC_000037826