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GCMS blank results for sample AE03614, March 28, 2002

Machine-extracted title · confidence 90%

Laboratory report documenting GCMS analysis of a method blank for sample AE03614 to verify analytical system cleanliness.

NYC-WTC_000037740–000037759

Folder label: “GCMS X 2/19/02 A 3/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02MAR08\03614.D Vial: 4 Acq On : 8 Mar 2002 6:03 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 Butanoic acid, 2-methyl-, m.. Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T.

4.64 0.11 ug/L 51119 1,4-Di chiorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Butanoic acid, 2-methyl-, methyl... 116 C6H1202 000868-57-5 83 2 Butanoic acid, 2-methyl-, methyl... 116 C6H1202 000868-57-5 83 3 Butanoic acid, 2-methyl-, methyl... 116 C6H1202 000868-57-5 74 4 Butanoic acid, 2-methyl-, methyl... 116 C6H12O2 000868-57-5 74 Abundance Scan 112 (4.638 min): 03514.D (-) m/z 57.00 100.00% 57 88

5000 41 N 4.20 4.40 4.60 4.80 5.00 01 ‘‘::1121/1f11122/1/1111/r ■ e • 49 “I“‘'i j 111/1/11111121171111127 ' l " •' ‘ “ I •“I “ I ‘ m/z 88.00 98.05% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #16441: Butanoic acid, 2-methyl-, methyl ester (CAS) $$ Me... 88 57

5000 i ’ ' ■ ■ i • ■ • ■ i ■ ■ ' ■ i • ■ ■ ■ i Tt.F 41 4.20 4.40 4.60 4.80 5.00 29 101 m/z 41.10 38.02% 69 Of ' ‘I''1111 n I" " I “ “ I ‘‘ l‘ ■"I'" —mdmmmp 111' ‘ +t Tpmp Tg—mumpr miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 Abundance

5000 #16439: Butanoic acid, 2-methyl-, methyl ester (CAS) $$ Me...

41 57 88 _ANa Mil 4.40 4.60 4.80 5.00 4.20 m/ z 59.00 35.53% 101 69 0!T’—E"6117 TT 1 ’217 U’’’11 Hmmmm + Tp m&-> Abundance 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 #16434: Butanoic acid, 2-methyl-, methyl ester $$ Butyric... 57 88 A--A 4.20 4.40 4.60 4.80 5.00 m/z 85.00 33.81% 5000 27 101 69 0 “i “ ■ ■ p ..|>...।....j.... ।.... j.... । - Ip TI 11.1 ■,.. 1, ■ T’ Ttrpuk”T122i111TTTII TT m/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 4.20 4.40 4.60 4.80 5.00

03514.D HP022102.M Fri Mar 15 10:09:23 2002 Page 7

NYC-WTC_000037750

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NYC-WTC_000037750Source: NYC Law Department, mirrored locally

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