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GCMS calibration table for TCLP method, Dec 2001

Machine-extracted title · confidence 100%

Quality reviewed GCMS calibration data listing surrogate compounds and retention times from December 14, 2001.

NYC-WTC_000036729–000036751

Folder label: “GCMS X 12/7/01 A 1/2/02

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Scanned page image, NYC-WTC_000036732
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NYC 9/11 Public Portal Document

LSC Area Percent Report

' Data File : M:\INSTRU-l\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Smoothing : OFF Filtering: 5 Sampling : 1 Min Area: 1 % of largest Peak Start Thrs: 0.2 Max Peaks: 100 Stop Thrs : 0 Peak Location: TOP

If leading or trailing edge < 100 prefer < Baseline drop else tangent > Peak separation: 5

Signal : TIC

peak R.T. first max last PK peak peak peak % of # min scan scan scan TY height area % max. total

1 7.594 274 278 292 rBV 349277 922644 2.66% 0.424% 2 11.670 715 722 735 rBV 2955917 7467032 21.53% 3.435% 3 11.835 735 740 753 rW 1938679 4525064 13.05% 2.081% 4 15.278 1109 1115 1133 rBV 4365279 9492636 27.37% 4.366% 5 16.517 1245 1250 1269 rBV 338932 844994 2.44% 0.389%

6 18.188 1427 1432 1445 rBV 134267 539198 1.55% 0.248% 7 20.557 1683 1690 1707 rBV 4678137 10261707 29.59% 4.720% 8 21.649 1802 1809 1816 rBV 561091 1081825 3.12% 0.498% 9 22.934 1944 1949 1957 rBV 461412 1120685 3.23% 0.515% 10 23.100 1957 1967 1971 rBV 9068914 24608034 70.95% 11.319%

11 23.999 2056 2065 2075 rW 3577502 7647247 22.05% 3.518% 12 24.357 2098 2104 2109 rBV 602054 1191749 3.44% 0.548% 13 24.982 2164 2172 2181 rBV2 4202594 9905288 28.56% 4.556% 14 25.119 2181 2187 2202 rW 2088026 4401424 12.69% 2.025% 15 25.303 2202 2207 2220 rW2 145846 515100 1.49% 0.237%

16 27.001 2386 2392 2405 rVB 1418586 2917087 8.41% 1.342% 17 30.049 2718 2724 2732 rBV 551382 1192295 3.44% 0.548% .18 32.197 2947 2958 2961 rBV 10004642 34682340 100.00% 15.953% 19 32.243 2961 2963 2973 rW 4273912 8969946 25.86% 4.126% 20 32.408 2974 2981 3000 rVB 3930887 9815971 28.30% 4.515%

21 33.005 3035 3046 3067 rBV2 8783669 31324600 90.32% 14.409% 22 •35.566 3319 3325 3345 rBV 582600 1815266 5.23% 0.835% 23 37.100 3484 3492 3513 rBV2 1997910 5840890 16.84% 2.687% 24 38.183 3598 3610 3620 rBV 4755491 18777424 54.14% 8.637% 25 38.376 3620 3631 3652 rVB 4483023 17538801 50.57% 8.068%

Sum of corrected areas: 217399247

NYC-WTC_000036732

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NYC-WTC_000036732Source: NYC Law Department, mirrored locally

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