GCMS comments for sample AD28159, Nov 2001

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Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2601\28153.D vial: 17 Acq On : 27 Nov 2001 2:21 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 3,6-Dioxa-2,4,5,7-tetrasilaoct Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

41.52 1.59 ug/1 283879 Perylene-dl2 37.12

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3,6-Dioxa-2,4,5,7-tetrasilaoctane, 294 C10H3002Si4 004342-25-0 28 2 Trisiloxane/ 1,1,1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 25 3 3-Isopropoxy-1,1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 25 4 2,6-Dimethy 1-3,4-bis(trimethylsilyl 311 C15H29NO2Si2 000000-00-0 17 Abundance 7 Scan 3973 (41.521 min): 28153.D (-) m/z 73.0.0 100.00% 73

147 221 5000 281 355 > ■ । ‘ । ■ ■ ■ ■ । ■ ■ ■ > । • ■ ■ ■ । 327, I , 401 429 41.20 41.40 41.60 41.80 43L 1 ' I ■ ' . 105.414 L 105 L ------- 350 400 450 500 550 m/z 147.00 61.41% mlz->____ 50 100 150 200 250 300 Abundance #41682:3,6-Dioxa-2,4,5,7-tetrasilaoctane, 2,2,4,4,5,5,7,7- 147 221

73 5000 _ PIT —PY 41.20 41.40 41.60 41.80 191 m/z 221.05 51.96%

m/z-> —

50 100 150 200 L Tr L 250 279

300 350 400 450 500 550 Abundance #74103: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trimet 73 147 —1—ITTT "AT 41.20 41.40 41.60 41.80 5000 m/z 207.00 26.86%

Ju 45 1117 - 207 249 P 281 369 wwWuw m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #60503: 3-lsopropoxy-1,1,1,7,7,7-hexamethyl-3,5,5-tris(trim 73 41.20 41.40 41.60 41.80 m/z 281.00 24.53% 5000 147 N k 221 ' 281 | 327 3f, A15 415 519 561 w -u T T m/z-> 50 100 150 200 250 300 350 400 450 500 550 41.20 41.40 41.60 41.80

28153.D GCMS1126.M Tue Nov 27 15:43:38 2001 Page 4

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